Structural features of monomeric octahedral d (2)-rhenium(V) monooxo complexes with oxygen atoms of bidentate-chelating acido (O,O)-ligands

摘要

The structural features of 39 mononuclear octahedral d (2)-rhenium(V) monooxo complexes (I-XXXIX) with oxygen atoms of bidentate-chelating (O,O) acido ligands (Lig) are considered. In 21 complexes (I-XXI), the O(lig) atoms are both in trans and cis positions to oxo ligands. In the other 18 complexes (XXI-XXXIX), both O(lig) atoms are in cis positions to the O(oxo) ligands.