Removal of U(VI) from aqueous solution using TiO2 modified β-zeolite

摘要

β-Zeolite was synthesized and modified with TiO2. The synthesized materials were characterized and used for removal of U(VI) from aqueous solutions. The influences of pH, contact time and temperature on U(VI) adsorption onto modified β-zeolite by TiO2 were studied by batch technique, and XPS was employed to analysed the experimental data. The dynamic process showed that the adsorption of U(VI) onto TiO2/β-zeolite matched the pseudo-second-order kinetics model, and the adsorption of U(VI) were significantly dependent on pH values. Through simulating the adsorption isotherms by Langmuir, Freundlich and Dubini–Radushkevich (D–R) models, it could be seen, respectively that the adsorption patterns of U(VI) onto TiO2/β-zeolite were mainly controlled by surface complexation, and the adsorption processes were endothermic and spontaneous. The modification of β-zeolite by TiO2 it shows a novel material for the removing of U(VI) from water environment for industrialized application.