Synergistic effect of vermiculite clay and ionizing irradiation on the physical and mechanical properties of polybutadiene rubber/ethylene propylene diene monomer nanocomposite

摘要

Blends of rubber-rubber have desired properties intermediated between two rubber matrices. On the other hand, polymer-clay nanocomposites have attracted the attention of many researchers and experimental results are presented in a large number of recent papers and patents because of the outstanding mechanical properties and low gas permeability that are achieved in many cases. Polymer-clay nanocomposites are a new class of mineral-field polymer that contain relatively small amounts (10%) of nanometer-sized clay particles. In this study, new nanocomposite materials were produced from the blend of polybutadiene rubber (BR) and ethylene propylene diene monomer rubber (EPDM), BR/EPDM (50/50) as matrix and organically modified vermiculite clay (VMT) by quaternary alkylammonium in different contents (3, 6, 9 and 12 phr) as the filler by using rubber mill then, the rubber nanocomposite sheets were irradiated at doses of 25, 50, 75, 100 and 150 kGy using gamma-radiation technique as a crosslinking tool. The prepared composites can be characterized by using various analytical techniques including X-ray diffractometer (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) as well as mechanical properties measurements.