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Effect of the Composition of Oxide Layers Formed by Plasma Electrolytic Oxidation on the Mechanism of Peroxide Oxidative Desulfurization

机译:等离子体电解氧化对过氧化物氧化脱硫机理形成的氧化物层组合物的影响

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摘要

The peroxide oxidation of thiophene, thioanisole, and dibenzothiophene in the presence of Ce, Zr, Ce + Zr, W, and W + Zn oxide layers formed by plasma electrolytic oxidation on the titanium surface was studied. The composition of the resulting composites was found to affect the activity and conversion of the organosulfur substrates. It was shown by the radical inhibition method that the composites differed in the mechanism of their catalytic action.
机译:研究了通过等离子体电解氧化在钛表面上的Ce,Zr,Ce + Zr,W和W + Zn氧化物层存在下的过氧化物氧化在Ce,Zr,Ce + Zr,W和W + Zn氧化物层中。 发现所得复合材料的组成影响有机硫衬底的活性和转化。 通过自由基抑制方法表示,复合材料在其催化作用的机制中不同。

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