The synthesis of new 1,3-oxazolidines and 1,3-oxazinanes containing (eta(6)-arene)tricarbonylchromium group based on condensation between aldehydes and amino alcohols

摘要

The condensation reactions of beta- and gamma-amino alcohols containing phenyl or (eta(6)-arene) tricarbonylchromium substituent with formaldehyde, acetaldehyde, benzaldehyde, and (eta(6)-benzaldehyde)tricarbonylchromium were studied. The resulting 1,3-oxazolidine and 1,3-oxazinane products were isolated in a pure form and identified by different physicochemical methods. The effect of (eta(6)-arene)tricarbonylchromium moiety on the reaction process was demonstrated.