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In situ synthesis of one eco‐friendly polyacrylic acid/zinc colloidal particles doped polyacrylic acid as an efficient corrosion inhibitor for iron

机译:原位合成一种环保聚丙烯酸/锌胶体颗粒掺杂聚丙烯酸作为铁的有效腐蚀抑制剂

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Abstract > Commonly used organic inhibitors face one common problem: Environmental friendliness and excellent inhibition efficiency cannot be simultaneously realized. Here, we report one facile method that can be used for the in situ synthesis of one stable polyacrylic acid/zinc colloidal particles (PZCPs) doped polyacrylic acid (PAA) through the electrostatic interaction between polyacrylic acid and Zn 2+ as a corrosion inhibitor of iron. The results of microstructure characterization indicated that the diameter of the colloidal particles was around 150?nm. The various electrochemical experimental results indicated that PZCPs doped PAA exhibited excellent inhibition efficiency, and the maximum inhibition efficiency was 82.3%. The PZCPs doped PAA exhibited higher inhibition efficiency than PAA because the adsorption ability of PZCPs doped PAA was stronger than that of PAA and the formed PZCPs doped PAA inhibition layer on the iron surface was thicker and denser than the PAA inhibition layer. Given the eco‐friendly, facile synthesis, excellent inhibition efficiency, and low price, this strategy to synthesize effective inhibitors will find widespread application in the anti‐corrosion industry. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> > 常用的有机抑制剂面临着一个常见问题:环境友好和出色的抑制效率不能同时实现。在此,我们通过聚丙烯酸和Zn之间的静电相互作用地报告了一种可用于原位合成一种稳定的聚丙烯酸/锌胶体颗粒(PZCPS)掺杂的聚丙烯酸(PAA)的方法。通过聚丙烯酸和Zn之间的静电相互作用 2 + </ sup> 作为铁的腐蚀抑制剂。微观结构表征的结果表明,胶体颗粒的直径约为150μm。各种电化学实验结果表明,PZCPS掺杂PAA表现出优异的抑制效率,最大抑制效率为82.3%。 PZCPS掺杂PAA表现出比PAA更高的抑制效率,因为PZCPS掺杂PAA的吸附能力强于PAA的吸附能力,并且在铁表面上的形成的PZCPS掺杂PAA抑制层比PAA抑制层更厚而更密集。鉴于环保,容易合成,优异的抑制效率和低价格,这种合成有效抑制剂的策略将在防腐工业中发现广泛应用。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24514/'>《Materials and Corrosion》</a> <b style="margin: 0 2px;">|</b><span>2020年第2期</span><b style="margin: 0 2px;">|</b><span>共13页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gao Xiang&option=202" target="_blank" rel="nofollow">Gao Xiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Weihua&option=202" target="_blank" rel="nofollow">Li Weihua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ma Houyi&option=202" target="_blank" rel="nofollow">Ma Houyi;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institute of Advanced Energy Materials and Chemistry School of Chemistry and Pharmaceutical EngineeringQilu University of Technology (Shandong Academy of Sciences)Jinan China;</p> <p>Key Laboratory of Marine Environmental Corrosion and Bio‐fouling Institute of OceanologyChinese Academy of SciencesQingdao China;</p> <p>Key Laboratory of Colloid and Interface Chemistry of State Education Ministry School of Chemistry and Chemical EngineeringShandong UniversityJinan China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7194.html" title="金属腐蚀与保护、金属表面处理">金属腐蚀与保护、金属表面处理;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=colloid&option=203" rel="nofollow">colloid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=corrosion inhibitor&option=203" rel="nofollow">corrosion inhibitor;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=EIS&option=203" rel="nofollow">EIS;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyacrylic acid&option=203" rel="nofollow">polyacrylic acid;</a> </p> <div class="translation"> 机译:胶体;腐蚀抑制剂;EIS;聚丙烯酸; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div 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<a href="/conference-cn-24601/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国感光学会第七次全国会员代表大会暨学术年会和第七届青年学术交流会 </a> <span> <span> . 2006</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314072239.html">聚(4-乙烯吡啶-丙烯酸丁酯)/聚(苯乙烯-丙烯酸丁酯-苯乙烯磺酸钠)高分子复合微球的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王伟栋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王伟栋</a> <span> . 2005</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201435441.html">聚甲基丙烯酸二甲胺基乙酯-聚甲基丙烯酸盐包裹氧化锌量子点及制备和应用</a> <b>[P]</b> . <span> 中国专利: CN101735383B </span> <span> . 2014.08.13</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120105984940.html">聚甲基丙烯酸二甲胺基乙酯-聚甲基丙烯酸盐包裹氧化锌量子点及制备和应用</a> <b>[P]</b> . <span> 中国专利: CN101735383A </span> <span> . 2010-06-16</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130479574402.html">Zinc alkaline electric battery - has cathode filled with paste contg. zinc particles, zinc oxides, electrolyte, polyacrylic acid and inorg(hydr)oxide</a> <b>[P]</b> . <span> 外国专利: <!-- 法国专利: --> FR2276699B1 </span> <span> . 1978-12-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:锌碱性电池-阴极充满糊状。锌颗粒,氧化锌,电解质,聚丙烯酸和无机(氢)氧化物 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130482706021.html">Zinc alkaline electric battery - has cathode filled with paste contg. zinc particles, zinc oxides, electrolyte, polyacrylic acid and inorg(hydr)oxide</a> <b>[P]</b> . <span> 外国专利: <!-- 法国专利: --> FR2276699A1 </span> <span> . 1976-01-23</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:锌碱性电池-阴极充满糊状。锌颗粒,氧化锌,电解质,聚丙烯酸和无机(氢)氧化物 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130437647044.html">Ingredients include active pharmaceutical ingredients in water-soluble vehicles selected from polyacrylamide / polyacrylic acid, polyacrylic acid, polyacrylic acid and their mixtures.</a> <b>[P]</b> . <span> 外国专利: <!-- --> UY29107A1 </span> <span> . 2006-04-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:成分包括水溶性媒介物中的活性药物成分,该媒介物选自聚丙烯酰胺/聚丙烯酸,聚丙烯酸,聚丙烯酸及其混合物。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div 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