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Long‐term exposure of austenitic steels and nickel‐based alloys in lignite‐biomass cofiring

机译：褐煤生物质COFIRING中长期暴露奥氏体钢和镍基合金

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Abstract >The aim of this study?was?to assess the long‐term impact that the addition of biomass provokes on superheater materials exposed to fireside corrosion environments. Alloys covering a broad range of commercially available materials were?investigated. Their corrosion kinetics under different corrosive deposits and atmospheres was evaluated, and their corrosion products analyzed to deepen understanding of the underlying corrosion mechanisms. Therefore, three nickel‐based alloys and three austenitic steels containing 20–24 wt.% Cr were?tested at 650°C for 7,000?hr. The long‐term exposure shows new mechanistic aspects of Type II hot corrosion that were revealed by accelerated material depletion. The formation of Ni–NiS eutectic and the formation of a Cr depleted zone close to the substrate corrosion product interface are indicative?of the breakaway occurrence. Differences in the corrosion behavior are related to the balance of Ni, Mo, Co, and Cr and can serve as the material selection argument. The evaluation concluded with the finding that alloys presenting Mo and Ni might be preferentially used in fireside corrosion in the presence of biomass, whereas the use of austenitic steels suffer less corrosion if no biomass is present in the corrosive atmosphere. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >本研究的目的？是评估在暴露于壁式腐蚀环境的过热器材料上添加生物质引起的长期影响。覆盖广泛的市售材料的合金是调查的。评估其在不同腐蚀性沉积物和大气下的腐蚀动力学，并分析了它们的腐蚀产品，以加深对潜在的腐蚀机制的理解。因此，三种基于镍基合金和含有20-24重量％的三个奥氏体钢。在650℃下测试7,000℃。长期曝光显示II型热腐蚀的新机制方面，其通过加速材料耗竭揭示。 Ni-NIS共晶和靠近衬底腐蚀产品界面的CR耗尽区的形成是指示性的。断裂发生。腐蚀行为的差异与Ni，Mo，Co和Cr的平衡有关，并且可以作为材料选择参数。该评价结束了，发现呈现Mo和Ni的合金可以在生物质存在下优先用于壁式腐蚀，而如果没有生物质存在于腐蚀性气氛中，则奥氏体钢的使用遭受更少的腐蚀。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24514/'>《Materials and Corrosion》</a> <b style="margin: 0 2px;">|</b><span>2019年第12期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Montero Xabier&option=202" target="_blank" rel="nofollow">Montero Xabier;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rudolphi Mario&option=202" target="_blank" rel="nofollow">Rudolphi Mario;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Galetz Mathias C.&option=202" target="_blank" rel="nofollow">Galetz Mathias C.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>DECHEMA‐ForschungsinstitutFrankfurt am Main Germany;</p> <p>DECHEMA‐ForschungsinstitutFrankfurt am Main Germany;</p> <p>DECHEMA‐ForschungsinstitutFrankfurt am Main Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7194.html" title="金属腐蚀与保护、金属表面处理">金属腐蚀与保护、金属表面处理;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=austenitic steels&option=203" rel="nofollow">austenitic steels;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=biomass cofiring&option=203" rel="nofollow">biomass cofiring;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hot corrosion&option=203" rel="nofollow">hot corrosion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lignite firing&option=203" rel="nofollow">lignite firing;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ni‐based alloys&option=203" rel="nofollow">Ni‐based alloys;</a> </p> <div class="translation"> 机译：奥氏体钢;生物量COFIRING;热腐蚀;褐煤烧制;Ni基合金; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023575143.html">Long‐term exposure of austenitic steels and nickel‐based alloys in lignite‐biomass cofiring</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Montero Xabier&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Montero Xabier,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rudolphi Mario&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Rudolphi Mario,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Galetz Mathias C.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Galetz Mathias C. </a> <a href="/journal-foreign-24514/" target="_blank" rel="nofollow" class="tuijian_authcolor">Materials and Corrosion .</a> <span>2019</span><span>,第12期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：褐煤生物质COFIRING中长期暴露奥氏体钢和镍基合金</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_journal-manufacturing-processes_thesis/0204113541819.html">Water cooling assisted laser dissimilar welding with filler wire of nickel-based alloy/austenitic stainless steel</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Dongjiang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wu Dongjiang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cheng Bo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Cheng Bo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Jun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Jun,</a> <a href="/journal-foreign-1120/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Manufacturing Processes .</a> <span>2019</span><span>,第Sepa期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：镍基合金/奥氏体不锈钢填充焊丝的水冷辅助激光异种焊接</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_corrosion-science_thesis/020418756145.html">Corrosion in austenitic steels and nickel-based alloys caused by liquid tin at high temperature</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Emmerich Thomas&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Emmerich Thomas,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schroer Carsten&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Schroer Carsten </a> <a href="/journal-foreign-13703/" target="_blank" rel="nofollow" class="tuijian_authcolor">Corrosion science .</a> <span>2017</span><span>,第MAY期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：液态锡在高温下对奥氏体钢和镍基合金的腐蚀</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-232774_thesis/020516811208.html">THE EFFECT OF IRRADIATION-INDUCED MATRIX BARRIER HARDENING ON IRRADIATION-ASSISTED STRESS CORROSION CRACKING (IASCC) IN AUSTENITIC STEELS AND NICKEL BASED ALLOYS</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=R.G. 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class="tuijian_auth tuijian_authcolor">,金鑫</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈恩普&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈恩普</a> <span> <a href="/conference-cn-52826/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国金属学会高温合金中微量元素的控制及其作用鉴定会 </a> <span> <span> . 1985</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/02031966426.html">褐煤残渣担载镍基催化剂在生物质气化中的应用</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘吉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘吉</a> <span> . 2015</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120109731732.html">适于钎焊超级奥氏体钢的具有高熔程的镍基合金</a> <b>[P]</b> . <span> 中国专利： CN107223079A </span> <span> . 2017-09-29</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120102694073.html">镍基合金热处理,镍基合金,和包括镍基合金的制品</a> <b>[P]</b> . <span> 中国专利： CN103958710A </span> <span> . 2014-07-30</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130448202497.html">Alloy production comprises coating base material made of austenitic nickel-based alloy or cobalt-based alloy or special steel on one or both sides with layer of aluminum or aluminum alloy</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE19957646A1 </span> <span> . 2001-05-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：合金生产包括在一侧或两侧用铝或铝合金层涂覆由奥氏体镍基合金或钴基合金或特种钢制成的基础材料 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130478176607.html">ELECTROLYTIC POLISHING METHOD FOR AUSTENITIC STAINLESS STEEL CONTAINING NICKEL AND NICKEL BASE ALLOY BY NEUTRAL ELECTROLYTE</a> <b>[P]</b> . <span> 外国专利： <!-- 日本专利： --> JPS5616699A </span> <span> . 1981-02-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：中性电解质对含镍和镍基合金的奥氏体不锈钢的电解抛光方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130443703289.html">Plated steel rolled material used for reinforcing concrete consists of a bimetal cast block made from a base material, and a surface layer made from ferritic or austenitic stainless steel containing chromium and nickel alloying additions</a> <b>[P]</b> . <span> 外国专利： <!-- 德国专利： --> DE10148635A1 </span> <span> . 2003-01-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于加固混凝土的镀钢板轧制材料，包括由基础材料制成的双金属铸块和由含铬和镍合金添加物的铁素体或奥氏体不锈钢制成的表面层。 </span> </p> </li> 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