Enhanced Performance of a Single Chamber Microbial Fuel Cell Using NiWO        <sub >4</sub>4        /Reduced Graphene Oxide Coated Carbon Cloth Anode

Geetanjali; Rani R.; Kumar S.

摘要

Abstract > Microbial fuel cell (MFC) technology has potential to generate bioelectricity. However, the low power density problem is considerably associated with anode materials and its performance. In this study, modified anodes for single chamber MFC (SMFC) have been developed using NiWO <sub>4</sub> impregnated on reduced graphene oxide (rGO) (NWG) composite. The analytical and morphological properties of rGO, NiWO <sub>4</sub> particles and NWG composites have been characterized by?FTIR, XRD, SEM and TEM. The electrochemical activity and capacitance of modified anode(s) are determined by cyclic?voltammetry and galvanostatics charge‐discharge, respectively. Modified NWG composite (2 mmol)‐carbon cloth (CC) anode has highest capacitance value of 47.27?±?0.18?F?cm ?2 . The maximum power density obtained by modified NWG composite (2 mmol)‐CC anode was observed to be 1128?±?42 mW m ?2 which was 6.57 times higher than the unmodified anode (171?±?8 mW m ?2 ). Electrochemical impedance spectra results indicate a substantial improvement in electron transfer between the microbes and the modified NWG composites‐CC anodes. The decrease in the internal resistance of SMFC system is observed due to the improved electrochemical capacitance and synergistic effect between NiWO <sub>4</sub> and rGO. In conclusion, modified NWG composites‐CC anodes enhance the performance considerably and show excellent potential in electrode surface electrocatalyst modifier in MFCs. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 微生物燃料电池（MFC）技术具有产生生物电性的潜力。然而，低功率密度问题与阳极材料及其性能相当相关。在该研究中，使用Niwo开发了单室MFC（SMFC）的改进的阳极 <sub> 4 </ sub> 浸渍在氧化物还原氧（RGO）（NWG）复合材料上。 rgo，Niwo的分析和形态学性质 <sub> 4 </ sub> 颗粒和NWG复合材料的特征在于？FTIR，XRD，SEM和TEM。改性阳极的电化学活性和电容分别通过循环α伏安法和GALVANOSTATICS电荷放电确定。改性的NWG复合材料（2mmol） - 碳布（CC）阳极具有最高电容值47.27？±0.18？F？cm ？2 </ sup> 。通过改性的NWG复合物（2mmol）-CC阳极获得的最大功率密度为1128？±42 mw m ？2 </ sup> 比未修饰的阳极高6.57倍（171？±8 mw m ？2 </ sup> ）。电化学阻抗谱结果表明微生物和改性NWG复合材料-CC阳极之间的电子转移的显着提高。由于NIWO之间的电化学电容和协同效应，观察到SMFC系统的内阻的降低 <sub> 4 </ sub> 和rgo。总之，改性的NWG复合材料-CC阳极显着增强了性能，并在MFC中的电极表面电催化剂改性剂中显示出优异的电位。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24199/'>《Fuel cells》</a> <b style="margin: 0 2px;">|</b><span>2019年第3期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Geetanjali&option=202" target="_blank" rel="nofollow">Geetanjali;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rani R.&option=202" target="_blank" rel="nofollow">Rani R.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kumar S.&option=202" target="_blank" rel="nofollow">Kumar S.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Motilal Nehru National Institute of Technology AllahabadDepartment of Biotechnology211004 Allahabad Uttar Pradesh India;</p> <p>Motilal Nehru National Institute of Technology AllahabadDepartment of Biotechnology211004 Allahabad Uttar Pradesh India;</p> <p>Indian Institute of Technology (BHU) VaranasiSchool of Biochemical Engineering221005 Varanasi Uttar Pradesh India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1817.html" title="电化学工业">电化学工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Anode Modification&option=203" rel="nofollow">Anode Modification;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Capacitance&option=203" rel="nofollow">Capacitance;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Microbial Fuel Cell&option=203" rel="nofollow">Microbial Fuel Cell;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nickel Tungstate&option=203" rel="nofollow">Nickel Tungstate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Power Density&option=203" rel="nofollow">Power Density;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Reduced Graphene Oxide&option=203" rel="nofollow">Reduced Graphene Oxide;</a> </p> <div class="translation"> 机译：阳极改性;电容;微生物燃料电池;镍钨酸盐;功率密度;减少的石墨烯氧化物; 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Enhanced Performance of a Single Chamber Microbial Fuel Cell Using NiWO 44 /Reduced Graphene Oxide Coated Carbon Cloth Anode

摘要

Enhanced Performance of a Single Chamber Microbial Fuel Cell Using NiWO ₄4 /Reduced Graphene Oxide Coated Carbon Cloth Anode