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首页> 外文期刊>Electroanalysis >Total Determination of Estrogenic Phenolic Compounds in River Water Using a Sensor Based on Reduced Graphene Oxide and Molecularly Imprinted Polymer
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Total Determination of Estrogenic Phenolic Compounds in River Water Using a Sensor Based on Reduced Graphene Oxide and Molecularly Imprinted Polymer

机译：基于氧化石墨烯氧化物和分子印迹聚合物的传感器，使用传感器全部测定河水中的雌激素酚类化合物

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Abstract > The contamination of water and wastewater by emerging pollutants, due to the anthropogenic activities, are an environmental problem that generates several negative impacts. In this range of species, steroids have gaining notoriety because their action of endocrine‐disruption. In this work, they are called estrogenic phenolic compounds (EPCs): estrone (E <sub>1</sub> ), estradiol (E <sub>2</sub> ), ethinyl estradiol (EE <sub>2</sub> ) and estriol (E <sub>3</sub> ), for determination using an electrochemical sensor based on reduced graphene oxide (rGO) and molecularly imprinted polymer (MIP). The analytical method developed, allied with the experimental and operational optimizations, proved to be effective for the total quantification of the EPCs in river water. The method shows sensitivity of 1.12?μA/μmol?L ?1 , detection limit of 26.8?nmol?L ?1 and linear range of 0.16–15?μmol?L ?1 . The similar electrochemical behavior of the four compounds studied (E <sub>1</sub> , E <sub>2</sub> , EE <sub>2</sub> and E <sub>3</sub> ) and the efficiency of the modified composite (rGO, MIP) in the fabrication of the sensor resulted in high electrical conductivity and selective adsorptivity, respectively. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</ title> >由于人为的活动，新兴污染物的水和废水污染是一种环境产生几个负面影响的问题。在这种种类的种类中，类固醇患有令人担忧的是，因为它们的内分泌破坏的作用。在这项工作中，它们称为雌激素酚类化合物（EPC）：Estrone（E <sub> 1 </ sub>），雌二醇（E <sub> 2 </ sub>），乙炔雌二醇（EE <sub> 2 </亚>）和雌醇（E <sub> 3 </ sub>），用于使用基于还原的氧化石墨烯（RGO）和分子印迹聚合物（MIP）的电化学传感器测定。通过实验和运营优化开发的分析方法证明是对河水中EPC的总量化有效。该方法显示敏感性为1.12ΩμA/μmol？l α1</ sup>，检测限为26.8Ω·nmol？l Δ1</ sup>和线性范围为0.16-15≤μmol？l ？1 </ sup>。所研究的四种化合物的类似电化学行为（E <sub> 1 </ sub>，E <sub> 2 </ sub>，ee <sub> 2 </ sub>和e <sub> 3 </ sub>）和改性复合材料（RGO，MIP）在传感器的制造中的效率分别产生高导电性和选择性吸附性。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-22546/'>《Electroanalysis》</a> <b style="margin: 0 2px;">|</b><span>2018年第9期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Braga Guilherme Bettio&option=202" target="_blank" rel="nofollow">Braga Guilherme Bettio;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Oliveira Ana Elisa Ferreira&option=202" target="_blank" rel="nofollow">Oliveira Ana Elisa Ferreira;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pereira Arnaldo César&option=202" target="_blank" rel="nofollow">Pereira Arnaldo César;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Departamento de Ciências NaturaisUniversidade Federal de S?o Jo?o del-Rei UFSJS?o Jo?o del-Rei ?mg 36307-352 Brazil;</p> <p>Departamento de Ciências NaturaisUniversidade Federal de S?o Jo?o del-Rei UFSJS?o Jo?o del-Rei ?mg 36307-352 Brazil;</p> <p>Departamento de Ciências NaturaisUniversidade Federal de S?o Jo?o del-Rei UFSJS?o Jo?o del-Rei ?mg 36307-352 Brazil;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4817.html" title="电化学、电解、磁化学">电化学、电解、磁化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Electrochemical sensor&option=203" rel="nofollow">Electrochemical sensor;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Emerging Contaminants&option=203" rel="nofollow">Emerging Contaminants;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Steroids&option=203" rel="nofollow">Steroids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Reduced Oxide Graphene (rGO)&option=203" rel="nofollow">Reduced Oxide Graphene (rGO);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Molecularly Imprinted Polymer (MIP)&option=203" rel="nofollow">Molecularly Imprinted Polymer (MIP);</a> </p> <div class="translation"> 机译：电化学传感器;新兴污染物;类固醇;还原氧化物石墨烯（RGO）;分子印迹聚合物（MIP）; 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