Effect of Exfoliated Graphene Defects on Thermal Conductivity of Water Based Graphene Nanofluids

摘要

In this work, sonication assisted exfoliated Graphene (Gr) was separated into five different suspensions using a systematic centrifugation scheme (4000-500 rpm) for the two different solvents N-Methyl-2-Pyrrolidone (NMP) and N, N-dimethylformamide (DMF). Gr dispersions in deionized water (DW) were prepared by the re-dispersion process with the aid of vacuum filtration. Systematic thermal conductivity (TC) measurements were conducted separately on the prepared Gr dispersion in DW with rising temperature ranging from 25 to 60°C. Defects in exfoliated Gr samples were identified in terms of intensity ratio of D and G band (I_D/I_G) of Raman spectroscopy. For a fixed time of sonication values of I_D/I_G were found considerably higher in higher centrifugation speed (rpm). This phenomenon was perceived for both of the solvents. However, obtained values of I_D/I_G for the exfoliated Gr in NMP (Gr-NMP) were lower than that of Gr exfoliated by DMF (Gr-DMF). Lowest values of I_D/I_G found for 500 rpm, were 0.697 and 0.879 for the Gr-NMP and Gr-DMF respectively. Effect of exfoliated Gr defects were evaluated on the TC of Gr dispersed DW nanofluids. At 60°C, TC of Gr-NMP dispersion in DW was obtained 1.146 W/m-K for I_D/I_G of 0.697 (500 rpm) and 0.935 W/m-K for I_D/I_G of 0.916 (4000 rpm). Similarly occurrence was also apparent for the Gr-DMF dispersion in DW.