Synthesis of Amides‐Functionalized POPs‐Supported Nano‐Pd Catalysts for Phosphine Ligand‐Free Heterogeneous Hydroaminocarbonylation of Alkynes

摘要

Abstract > Development of an approach for synthesis of efficient heterogeneous catalyst toward carbonylation reaction remains a challenge. Herein, we report our results of design and precise synthesis of amide‐functionalized porous organic polymers (POPs) supported nano‐Pd, and its applying in the first example of heterogeneous palladium‐catalyzed hydroaminocarbonylation of alkynes under phosphine ligand‐free conditions. A wide range of terminal alkynes and amines with various functional groups are smoothly converted into the corresponding branched α , β ‐unsaturated amides in moderate to good yields with high regioselectivity. The good catalytic performance of amides‐functionalized POPs supported nano‐Pd catalyst should be attributed to fine regulation of the catalytically active sites of the heterogeneous catalyst at the molecular level. The present study provided meaningful insights to design heterogeneous catalysts for phosphine ligand‐free carbonylation reaction. > <blockFixed type="graphic"> <mediaResourceGroup> <mediaResource alt="image" href="urn:x-wiley:16154150:media:adsc202000242:adsc202000242-toc-0001"/> </mediaResourceGroup> </blockFixed> </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 开发合成有效的异质催化剂朝向羰基化反应的方法仍然是挑战。在此，我们报告了我们的设计和精确合成酰胺官能化多孔有机聚合物（POPS）的纳米PD的结果，以及其在磷酸酯条状条件下炔烃的非均相钯催化的羟氨基羰基化的第一实施例中的应用。具有各种官能团的各种末端炔醇和胺在相应的分支中平滑地转换成相应的分支 α</ i> 那 β</ i> - 饱和酰胺中的中等至良好的产量高，具有高区域选择性。酰胺官能化孔的良好催化性能负载纳米Pd催化剂应归因于在分子水平的非均相催化剂的催化活性位点的微调。本研究提供了有意义的见解，用于设计无异构催化剂的膦配体无碳化物反应。 </ p> > <blockfixed type =“图形”> <mediaresourcegroup> <MediareSource Alt =“图像”Href =“URN：X-Wiley：16154150：介质：ADSC202000242：ADSC202000242-TOC-0001”/> </ mediaresourcegroup> </ blockfixed> </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-19407/'>《Advanced synthesis & catalysis》</a> <b style="margin: 0 2px;">|</b><span>2020年第12期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/238.html" title="化学工业">化学工业;</a><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a><a href="https://www.zhangqiaokeyan.com/clc/7777.html" title="化学反应过程">化学反应过程;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hydroaminocarbonylation&option=203" rel="nofollow">Hydroaminocarbonylation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Phosphine Ligand-Free&option=203" rel="nofollow">Phosphine Ligand-Free;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Porous organic polymers&option=203" rel="nofollow">Porous organic polymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Surface functional groups&option=203" rel="nofollow">Surface functional groups;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heterogeneous catalysis&option=203" rel="nofollow">Heterogeneous catalysis;</a> </p> <div class="translation"> 机译：羟氨基羰基化;无膦配体;多孔有机聚合物;表面官能团;异构催化; 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=廖学品&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,廖学品</a> <span> <a href="/conference-cn-64499/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第五届全国化学工程与生物化工年会 </a> <span> <span> . 2008</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314314684.html">具有生物活性的N，N’-双取代-α-氨基酰胺衍生物的合成(Ⅰ)：N-2-取代呋喃甲酰基-α-氨基酸的合成;(Ⅱ)：N，N’-双取代-α-氨基酰胺衍生物的合成及生物活性测定</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=胥杨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 胥杨</a> <span> . 2009</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201943297.html">聚氨基酚和二氯二茂钛非均相催化合成β-氨基羰基化合物的方法</a> <b>[P]</b> . <span> 中国专利： CN104140374B </span> <span> . 2016.02.17</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120102770166.html">聚氨基酚和二氯二茂钛非均相催化合成β-氨基羰基化合物的方法</a> <b>[P]</b> . <span> 中国专利： CN104140374A </span> <span> . 2014-11-12</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130459883164.html">New bis:di:alkyl-amino-phosphine oxido-amino-alkyl-tri:alkoxy-silane cpds. supported organo-amino-phosphine oxide catalyst - used in disproportionation of aryl- or alkyl-halo-di:silane cpds. and prepn. of new cpds. and catalyst</a> <b>[P]</b> . <span> 外国专利：  DE4207299A1 </span> <span> . 1993-11-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：新的双：二：二：烷基-氨基膦氧化-氨基-烷基-三：烷氧基-硅烷cpds。负载型有机氨基氧化膦催化剂-用于芳基或烷基卤代二：硅烷cpds歧化和准备。新的cpds。和催化剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130469569239.html">SYNTHESIS OF AMIDE ACIDS BY USE OF COBALT CATALYST AND BIDENTATE PHOSPHINE LIGAND</a> <b>[P]</b> . <span> 外国专利：  JPS63101354A </span> <span> . 1988-05-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用钴催化剂和二齿膦配体合成酰胺酸 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130442537286.html">Phosphine compound, transition metal complex containing the same phosphine compound as ligand and asymmetric synthesis catalyst containing the complex</a> <b>[P]</b> . <span> 外国专利：  US6717016B2 </span> <span> . 2004-04-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：膦化合物，包含与配体相同的膦化合物的过渡金属配合物和包含该配合物的不对称合成催化剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 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