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Hierarchical Nickel Cobaltate/Manganese Dioxide Core‐Shell Nanowire Arrays on Graphene‐Decorated Nickel Foam for High‐Performance Supercapacitors

机译:层次镍钴酸盐/二氧化锰芯壳纳米线阵列,用于高性能超级电容器的石墨烯装饰镍泡沫

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Abstract > Hierarchical NiCo <sub>2</sub> O <sub>4</sub> @MnO <sub>2</sub> core‐shell nanowire arrays have been synthesized on graphene‐nickel foam as binder‐free electrodes. The thickness of MnO <sub>2</sub> nanosheets can be controlled by different hydrothermal reaction times, and a whole array of unique NiCo <sub>2</sub> O <sub>4</sub> @MnO <sub>2</sub> nanostructures have been synthesized and investigated successfully for supercapacitor applications. The graphene deposited on nickel foam can enhance the electrical conductivity of electrode materials and strengthen corrosion resistance of the current collector. As a result, NiCo <sub>2</sub> O <sub>4</sub> @MnO <sub>2</sub> core‐shell arrays electrode exhibits an ultra‐high specific capacitance of 2125?F?g ?1 at a current density of 1?A?g ?1 , outstanding cycling stability (93.4?% of its initial value after 5000 cycles) and good rate performance. In addition, an asymmetric supercapacitor based on NiCo <sub>2</sub> O <sub>4</sub> @MnO <sub>2</sub> as the positive electrode and activated graphene (AG) as the negative electrode achieves an energy density of 27.8?Wh?kg ?1 at a power density of 400.3?W?Kg ?1 . These notable findings suggest that the unique NiCo <sub>2</sub> O <sub>4</sub> @MnO <sub>2</sub> core‐shell nanostructure on graphene‐nickel foam is a potential candidate for application as a high‐performance supercapacitor electrode. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml:lang =“en”> <标题类型=“main”>抽象</ title> > 等级尼科 <sub> 2 </ sub> O. <sub> 4 </ sub> @mno. <sub> 2 </ sub> 核 - 壳纳米线阵列已在石墨烯 - 镍泡沫上合成为无粘合剂电极。 mno的厚度 <sub> 2 </ sub> 纳米片可以由不同的水热反应时间控制,以及一系列独特的Nico阵列 <sub> 2 </ sub> O. <sub> 4 </ sub> @mno. <sub> 2 </ sub> 已合成纳米结构并成功研究了超级电容器应用。沉积在镍泡沫上的石墨烯可以增强电极材料的电导率,并强化集电器的耐腐蚀性。结果,Nico <sub> 2 </ sub> O. <sub> 4 </ sub> @mno. <sub> 2 </ sub> 核心壳阵列电极表现出2125〜2的超高比电容 ?1 </ sup> 在电流密度为1?a?g ?1 </ sup> ,出色的循环稳定性(在5000次循环后的初始值的93.4?%)和良好的速率性能。此外,基于Nico的非对称超级电容器 <sub> 2 </ sub> O. <sub> 4 </ sub> @mno. <sub> 2 </ sub> 作为正极和活性石墨烯(Ag),因为负电极实现的能量密度为27.8?wh?kg ?1 </ sup> 功率密度为400.3?w?kg ?1 </ sup> 。这些值得注意的发现表明,独特的尼科 <sub> 2 </ sub> O. <sub> 4 </ sub> @mno. <sub> 2 </ sub> 石墨烯 - 镍泡沫上的核 - 壳纳米结构是应用作为高性能超级涂物电极的潜在候选者。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2017年第9期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Hao&option=202" target="_blank" rel="nofollow">Chen Hao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hsieh Chien‐Kuo&option=202" target="_blank" rel="nofollow">Hsieh Chien‐Kuo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Yue&option=202" target="_blank" rel="nofollow">Yang Yue;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiao Ying&option=202" target="_blank" rel="nofollow">Liu Xiao Ying;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lin Che‐Hsien&option=202" target="_blank" rel="nofollow">Lin Che‐Hsien;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tsai Chuen‐Horng&option=202" target="_blank" rel="nofollow">Tsai Chuen‐Horng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wen Zhong Quan&option=202" target="_blank" rel="nofollow">Wen Zhong Quan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dong Fan&option=202" target="_blank" rel="nofollow">Dong Fan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Yu Xin&option=202" target="_blank" rel="nofollow">Zhang Yu Xin;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Material Science and EngineeringChongqing UniversityChongqing 400044 P.R. China;</p> <p>Department of Material EngineeringMing Chi University of TechnologyNew Taipei city 24301 Taiwan;</p> <p>College of Material Science and EngineeringChongqing UniversityChongqing 400044 P.R. China;</p> <p>College of Material Science and EngineeringChongqing UniversityChongqing 400044 P.R. China;</p> <p>Department of Engineering and System ScienceNational Tsing Hua UniversityHsinchu 30013 Taiwan;</p> <p>Department of Engineering and System ScienceNational Tsing Hua UniversityHsinchu 30013 Taiwan;</p> <p>National Key Laboratory of Fundamental Science of Micro/Nano-Devices and System TechnologyChongqing UniversityChongqing 400044 P.R. China;</p> <p>Chongqing Key Laboratory of Catalysis and Functional Organic Molecules College of Environmental and Biological EngineeringChongqing Technology and Business UniversityChongqing 400067 P. R. China;</p> <p>College of Material Science and EngineeringChongqing UniversityChongqing 400044 P.R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrode materials&option=203" rel="nofollow">electrode materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphene&option=203" rel="nofollow">graphene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=manganese dioxide&option=203" rel="nofollow">manganese dioxide;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nickel cobaltate&option=203" rel="nofollow">nickel cobaltate;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=supercapacitors&option=203" rel="nofollow">supercapacitors;</a> </p> <div class="translation"> 机译:电极材料;石墨烯;二氧化锰;镍钴酸盐;超级电容器; 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