Thermodynamics of mixtures containing the CO and OH groups .3. DISQUAC predictions on VLE and H-E for ternary mixtures containing 1-alkanols, n-alkanones, and one organic solvent

摘要

Thermodynamic properties: vapor-liquid equilibria, VLE, or excess enthalpies, H-E, for a set of 21 ternary mixtures of the type 1-alkanol + n-alkanone + organic solvent are studied in the framework of the DISQUAC group contribution model. This treatment is extended to the binaries involved. The DISQUAC analysis is developed on the basis of binary interactions only, that is, ternary interactions are neglected. Most of the interchange coefficients needed are available in the literature. The average relative standard deviations are 0.026 for pressure in the VLE (12 systems) and 0.098 in the H-E (9 systems). The discrepancies observed are briefly discussed.