Hybrid organosiloxane material/metal oxide composite as efficient anticorrosive coatings for mild steel in a saline medium

Suleiman Rami K.; Kumar A. Madhan; Sorour Ahmad A.; Al‐Badour Fadi A.; El Ali Bassam

摘要

ABSTRACT > Hybrid sol–gel materials have been found very promising anticorrosive coatings for metal substrates. In this article, the synthesis of novel hybrid organic‐inorganic sol–gel polymer; starting from tetraethyl orthosilicate, (3‐aminopropyl) trimethoxysilane, dimethoxy‐methyl‐octadecylsilane and polydimethylsiloxane, silanol terminated precursors, is reported. The hybrid polymer has been further loaded individually as well with five different metal oxides, then deposited on mild steel panels. All cured coating formulations have been characterized using thermogravimetric analysis, contact angle measurements, electrochemical impedance spectroscopy, vicker‐microhardness, surface roughness, and critical load analyses. Results have revealed that the parent coating exhibits excellent thermal stability and hydrophobic nature with minor observed changes on the two properties for the metal oxide‐loaded coatings. Electrochemical impedance and visual inspection results indicated excellent corrosion protection performance for all metal oxide composite coatings (except magnesium oxide) on steel when immersed in 3.5% NaCl solution for a prolonged time. Furthermore, the coating containing molybdenum oxide exhibited a maximum hardness, homogeneity, and adherence to the steel surface. The developed coating formulations in this study can be considered as a promising alternative to the currently‐used toxic chromate and phosphate coatings. ? 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 134 , 46718 </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><抽象的xmlns = “http://www.wiley.com/namespaces/wiley” 类型= “主”> <标题类型= “主”>摘要</ TITLE> <P>混合溶胶 - 凝胶材料已经被发现非常希望用于金属基底防锈涂料。在本文中，新的杂化有机 - 无机溶胶 - 凝胶聚合物的合成;据报道从原硅酸四乙酯起始，（3-氨基丙基）三甲氧基硅烷，二甲氧基甲基 - 十八烷基硅烷和聚二甲基硅氧烷，硅烷醇封端的前体。杂化聚合物已被进一步个别地装载以及具有五个不同的金属氧化物，然后沉积在软钢面板。所有固化涂料配方已经使用热重分析，接触角测量，电化学阻抗谱，维氏-显微硬度，表面粗糙度，和临界载荷分析表征。结果可知，与母体涂层显示出优异的热稳定性和疏水性有轻微观察到对两个属性的金属氧化物负载的涂料的变化。浸在3.5％NaCl溶液在延长的时间时电化学阻抗和目视检查结果表明优异的腐蚀保护性能上钢所有金属氧化物的复合涂层（除了氧化镁）。此外，含有氧化钼的涂层表现出最大的硬度，均匀性，和遵守钢表面。在本研究中开发的涂料制剂可以被认为是有希望的替代目前所使用的有毒的铬酸盐和磷酸盐涂层。还是2018 Wiley期刊，Inc.J.Phill。聚合物。 SCI。 <B> 2018 </ B>，<I> 134 </ i>的，46718 </ p> </抽象> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33581/'>《Journal of Applied Polymer Science》</a> <b style="margin: 0 2px;">|</b><span>2018年第40期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Suleiman Rami K.&option=202" target="_blank" rel="nofollow">Suleiman Rami K.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kumar A. Madhan&option=202" target="_blank" rel="nofollow">Kumar A. Madhan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sorour Ahmad A.&option=202" target="_blank" rel="nofollow">Sorour Ahmad A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Al‐Badour Fadi A.&option=202" target="_blank" rel="nofollow">Al‐Badour Fadi A.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=El Ali Bassam&option=202" target="_blank" rel="nofollow">El Ali Bassam;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Center of Research Excellence in CorrosionKing Fahd University of Petroleum and Minerals (KFUPM)Dhahran 31261 Saudi Arabia;</p> <p>Center of Research Excellence in CorrosionKing Fahd University of Petroleum and Minerals (KFUPM)Dhahran 31261 Saudi Arabia;</p> <p>Center of Research Excellence in CorrosionKing Fahd University of Petroleum and Minerals (KFUPM)Dhahran 31261 Saudi Arabia;</p> <p>Mechanical Engineering DepartmentKing Fahd University of Petroleum and Minerals (KFUPM)Dhahran 31261 Saudi Arabia;</p> <p>Chemistry DepartmentKing Fahd University of Petroleum and Minerals (KFUPM)Dhahran 31261 Saudi Arabia;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1821.html" title="高分子化合物工业（高聚物工业）">高分子化合物工业（高聚物工业）;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=coatings&option=203" rel="nofollow">coatings;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemistry&option=203" rel="nofollow">electrochemistry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mechanical properties&option=203" rel="nofollow">mechanical properties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polycondensation&option=203" rel="nofollow">polycondensation;</a> </p> <div class="translation"> 机译：涂料;电化学;机械性能;缩聚; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020588839.html">Hybrid organosiloxane material/metal oxide composite as efficient anticorrosive coatings for mild steel in a saline medium</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Suleiman Rami K.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Suleiman Rami K.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kumar A. 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