A novel, high-efficiency and'/> Construction of β-Trifluoromethyl Enol Ether via Base-Promoted C–O Coupling and Rearrangement of Hydrogen Atom
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Construction of β-Trifluoromethyl Enol Ether via Base-Promoted C–O Coupling and Rearrangement of Hydrogen Atom

机译：通过碱基促进的C-O耦合和氢原子的重排构造β-三氟甲基烯醚的构建

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摘要

src="http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/joceah/2017/joceah.2017.82.issue-9/acs.joc.7b00396/20170501/images/medium/jo-2017-00396t_0006.gif">A novel, high-efficiency and high-selectivity construction of β-trifluoromethyl enol ether via base-induced/promoted C–O coupling of trifluoromethylated vinyl chloride and phenols is presented with a broad substrate scope. The reaction mechanism, especially the significantly high selectivity, was excavated and understood via DFT calculation and is well supported by the experimental observation.
机译：src =“http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/joceah/2017/joceah.2017.82.issue-9/acs.joc.7b00396/20170501/images/medium / jo-2017-00396t_0006.gif"2Aa通过碱诱导/促进的三氟甲基化氯乙烯和酚的β-三氟甲基烯醇醚的新颖，高效率和高选择性施加均具有宽的基材范围 。 通过DFT计算挖掘和理解反应机理，尤其是显着高的选择性，并通过实验观察得到很好的支持。

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  • 来源
    《The Journal of Organic Chemistry》 |2017年第9期|共8页
  • 作者

    Kun Dai; Kuan Wang; Yang Li; Jian-Gang Chen; Zhong-Wen Liu; Jian Lu; Zhao-Tie Liu;

  • 作者单位

    Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) and School of Chemistry and Chemical Engineering Shaanxi Normal University Xi’an 710119 China;

    Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) and School of Chemistry and Chemical Engineering Shaanxi Normal University Xi’an 710119 China;

    State Key Laboratory of Fluorine and Nitrogen Chemicals Xi’an Modern Chemistry Research Institute Xi’an 710065 China;

    Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) and School of Chemistry and Chemical Engineering Shaanxi Normal University Xi’an 710119 China;

    Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) and School of Chemistry and Chemical Engineering Shaanxi Normal University Xi’an 710119 China;

    State Key Laboratory of Fluorine and Nitrogen Chemicals Xi’an Modern Chemistry Research Institute Xi’an 710065 China;

    Key Laboratory of Applied Surface and Colloid Chemistry (Ministry of Education) and School of Chemistry and Chemical Engineering Shaanxi Normal University Xi’an 710119 China;

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  • 正文语种 eng
  • 中图分类 有机化学;
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