We report an electrophilic c'/> CuX-Activated N-Halosuccinimide: Synthesis of 3-Haloquinolines via Electrophilic Cyclization of Alkynyl Imines
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CuX-Activated N-Halosuccinimide: Synthesis of 3-Haloquinolines via Electrophilic Cyclization of Alkynyl Imines

机译：Cux-activated N - 卤代琥珀酰亚胺：通过炔基亚胺的亲电环化合成3-卤代喹啉

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摘要

src="http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/joceah/2017/joceah.2017.82.issue-9/acs.joc.7b00131/20170501/images/medium/jo-2017-00131r_0009.gif">We report an electrophilic cyclization of alkynyl imines to afford polysubstituted 3-haloquinolines using CuX-activated N-halosuccinimdes (NXS) as electrophiles. Control experiments demonstrated that the NXS/CuX system might be more active than single NXS and could be applied in the electrophilic cyclization of electron- deficient substrates.
机译：src =“http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/joceah/2017/joceah.2017.82.issue-9/acs.joc.7b00131/2017050501/images/medium /jo-2017-00131R_0009.gif">我们报告炔基亚胺的亲电环化，以使用CUX-活化的 -Halosucinimdes（NXS）作为电子手柄提供多助化的3-卤喹啉。 对照实验表明，NXS / CUX系统可能比单个NXS更有效，并且可以应用于电子缺陷基材的亲电环化。

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  • 来源
    《The Journal of Organic Chemistry》 |2017年第9期|共6页
  • 作者

    Le Liu; Dianpeng Chen; Jinzhong Yao; Qianshou Zong; Jianbo Wang; Hongwei Zhou;

  • 作者单位

    Department of Chemistry Zhejiang University (Campus Xixi) Hangzhou 310028 People’s Republic of China;

    Department of Chemistry Zhejiang University (Campus Xixi) Hangzhou 310028 People’s Republic of China;

    College of Biological and Chemical Sciences and Engineering Jiaxing University Jiaxing 314001 People’s Rupublic of China;

    College of Biological and Chemical Sciences and Engineering Jiaxing University Jiaxing 314001 People’s Rupublic of China;

    College of Biological and Chemical Sciences and Engineering Jiaxing University Jiaxing 314001 People’s Rupublic of China;

    Department of Chemistry Zhejiang University (Campus Xixi) Hangzhou 310028 People’s Republic of China;

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  • 正文语种 eng
  • 中图分类 有机化学;
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