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Oxidative Radical Intermolecular Trifluoromethylthioarylation of Styrenes by Arenediazonium Salts and Copper(I) Trifluoromethylthiolate

机译:氧化亚氮盐和铜(I)三氟甲基盐的氧化自由基分子三氟甲基乙基亚芳基亚芳基

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摘要

An efficient oxidative radical intermolecular trifluoromethylthioarylation of styrenes with arenediazonium salts and copper(I) trifluoromethylthiolate under mild conditions is described for the first time. The reactions provide good yields of the corresponding trifluoromethylthioarylation products with broad substrate scope and excellent functional group compatibility.
机译:首次描述了在温和条件下用氧化氮盐和铜(I)三氟甲基硫酸盐的苯乙烯的有效氧化自由基三氟甲基亚芳基。 反应提供具有宽基底范围和优异的官能团相容性的相应三氟甲基乙基亚芳基产物的良好产率。

著录项

  • 来源
    《The Journal of Organic Chemistry》 |2018年第10期|共8页
  • 作者单位

    Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 China;

    Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 China;

    School of Chemical Engineering and Food Science Zhengzhou Institute of Technology 18 Yingcai Street Zhengzhou 450044 China;

    Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 China;

    Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 China;

    Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences Chinese Academy of Sciences 345 Lingling Road Shanghai 200032 China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 有机化学;
  • 关键词

  • 入库时间 2022-08-19 18:55:37

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