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Measurement of electron affinity of iridium atom and photoelectron angular distributions of iridium anion

机译:铱星铱原子和光电子角分布的电子亲和力的测量

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Published under license by AIP Publishing. The latest electron affinity value of an iridium atom is 1.564 36(15) eV, determined via a method based on the Wigner threshold law by Bilodeau and co-workers. However, they observed a significant deviation from the Wigner threshold law in the threshold photodetachment experiment. To address this dilemma, we conducted high-resolution photoelectron spectroscopy of Ir- via the slow-electron velocity-map imaging method in combination with an ion trap. The electron affinity of Ir was measured to be 12 614.97(9) cm(-1) or 1.564 057(11) eV. We find that the Wigner threshold law is still valid for the threshold photodetachment of Ir- through a p-wave fitting of the photodetachment channel Ir-5d86s23F4 -> Ir5d86sb4F9/2. The photoelectron angular distributions of photodetachment channels Ir-5d86s23F4 -> Ir5d76s2a4F9/2 and Ir-5d86s23F4 -> Ir5d86sb4F9/2 were also investigated. The behavior of anisotropy parameter beta indicates a strong interaction between the two channels. Moreover, the energy level P-3(2) of Ir-, which was not observed in the previous works, was experimentally determined to be 4163.24(16) cm(-1) above the ground state.
机译:通过AIP发布在许可证下发布。铱星原子的最新电子亲和力值为1.564 36(15 )EV,通过基于Bilodeau和Co-Workers基于Wigner阈值法的方法确定。然而,他们观察到阈值光致张解实验中的Wigner阈值法的显着偏差。为了解决这种困境,我们通过慢电子速度映射成像方法与离子阱组合进行了高分辨率的光电子光谱。测量IR的电子亲和力为12 614.97(9)cm(-1)或1.564 057(11)EV。我们发现,Wigner阈值定律仍然有效地用于IR-通过光托管频道IR-5D86S23F4 - > IR5D86SB4F9 / 2的P波拟合的阈值光折叠。还研究了光电迁移通道IR-5D86S23F4 - > IR5D76S2A4F9 / 2和IR-5D86S23F4 - > IR5D86SB4F9 / 2的光电子角分布。各向异性参数β的行为表示两个通道之间的强相互作用。此外,在先前作品中未观察到的IR-的能量水平P-3(2)在实验确定为地面上方4163.24(16 )cm(-1)。

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