Thermogravimetric analysis of soot combustion in the presence of ash and soluble organic fraction

摘要

Soot (Printex U, PU) combustion in the presence of ash and soluble organic fraction (SOF) was studied by thermogravimetric analysis (TGA). The comprehensive combustion index, combustion stability index and peak temperature were collected to evaluate the combustion performance of soot/ash/SOF mixtures. Compared with SiO2, Fe(2)O(3)and CaSO(4)nanoparticles, ZnO nanoparticles efficiently accelerate soot combustion with excellent oxygen carrying abilities. When the weight ratio of the PU/ZnO mixture is 1 : 1, this acceleration effect is maximized in the soot combustion process. The comprehensive combustion and combustion stability indices increase from 0.667 x 10(-7)%(2)min(-2)degrees C(-3)and 23.53 x 10(5)to 1.296 x 10(-7)%(2)min(-2)degrees C(-3)and 39.53 x 10(5), compared to pure PU, respectively. Compared with the PU/ZnO mixture, the soot combustion had inferior results after adding two oils as the simulative SOF. The 15W lubricant had the minimum negative impact compared to 0# diesel fuel. The comprehensive combustion and combustion stability indices reach the maximum values of 1.074 x 10(-7)%(2)min(-2)degrees C(-3)and 33.29 x 10(5)at the 1 : 1 : 0.1 weight ratio of PU/ZnO/15W, which grew by 62% and 42% compared to pure PU, respectively. This work contributes to an understanding of the combined effect of ash and SOF on soot combustion.