One-pot synthesis of a PtPd dendritic nanocube cage superstructure on graphenes as advanced catalysts for oxygen reduction

摘要

How to use Pt economically and efficiently in the oxygen reduction reaction (ORR) is of theoretical and practical significance for the industrialization of the proton-exchange membrane fuel cells. In order to minimize Pt consumption and optimize the ORR performance, the ORR catalysts are recommended to be designed as a porous nanostructure. Herein, we report a one-pot solvothermal strategy to prepare PtPd dendritic nanocube cages via a galvanic replacement mechanism triggered by an I- ion. These PtPd alloy crystals are nanoporous, and uniformly dispersed on reduced graphene oxides (RGOs). The size of the PtPd dendritic nanocube cages can be easily tuned from 20-80 nm by controlling their composition. Their composition is optimized to be 1:5 Pt/Pd atomic ratio for these RGO-supported PtPd dendritic nanocages. This catalyst shows superior ORR performance with a specific activity of 2.01 mA cm(-2) and a mass activity of 4.45 A mg(-1) Pt, far above those for Pt/C catalysts (0.288 mA cm(-2) for specific activity, and 0.21 A mg(-1) Pt for mass activity). In addition to ORR activity, it also exhibits robust durability with almost negligible decay in ORR mass activity after 10 000 voltammetric cycling.