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Polypyrrole coated niobium disulfide nanowires as high performance electrocatalysts for hydrogen evolution reaction

机译:聚吡咯涂覆铌二硫化物纳米线作为高性能电催化剂,用于氢进化反应

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摘要

Developing an environmentally friendly and low-cost approach to improve electrocatalytic activity for hydrogen evolution reaction (HER) has drawn wide attention due to its significant value and challenge. NbS2-based materials exhibit high performance catalytic activity in electrochemical area, but its poor stability and synthetic difficulty limits its development and application. This work reports on the enhancement of HER performance through the utilization of conductive polymer polypyrrole (Ppy) on NbS2 nanowires as electrocatalysts, which can be easily prepared. The Ppy coated NbS2 nanowires obtain excellent catalytic activity for HER with low onset potential (-56 mV) and much lower overpotential (-219 mV) at a current of -10 mA cm(-2) compared with bare NbS2 nanowires.
机译:制定环保和低成本的方法,以改善氢气进化反应的电催化活性(她)由于其显着的价值和挑战而引起了广泛的关注。 基于NBS2的材料在电化学区域表现出高性能催化活性,但其稳定性差和合成难度限制了其开发和应用。 这项工作通过在NBS2纳米线上利用导电聚合物聚合物(PPY)作为电催化剂来提高她的性能,可以容易地制备。 与裸NBS2纳米线相比,PPY涂覆的NBS2纳米线以低发作电位(-56mV),在-10mA cm(-2)的电流下,在-10mA cm(-2)的电流下,低得次催化活性。

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  • 来源
    《Nanotechnology》 |2019年第40期|共7页
  • 作者单位

    Shenzhen Univ Coll Phys &

    Optoelect Engn Dept One Inst One City One Country One Int Collab Minist Educ Shenzhen 518060 Peoples R China;

    Singapore Univ Technol &

    Design Pillar Engn Prod Dev 8 Somapah Rd Singapore 487371 Singapore;

    Singapore Univ Technol &

    Design Pillar Engn Prod Dev 8 Somapah Rd Singapore 487371 Singapore;

    Singapore Univ Technol &

    Design Pillar Engn Prod Dev 8 Somapah Rd Singapore 487371 Singapore;

    Shenzhen Univ Coll Phys &

    Optoelect Engn Dept One Inst One City One Country One Int Collab Minist Educ Shenzhen 518060 Peoples R China;

    Singapore Univ Technol &

    Design Pillar Engn Prod Dev 8 Somapah Rd Singapore 487371 Singapore;

    Singapore Univ Technol &

    Design Pillar Engn Prod Dev 8 Somapah Rd Singapore 487371 Singapore;

    Shenzhen Univ Coll Phys &

    Optoelect Engn Dept One Inst One City One Country One Int Collab Minist Educ Shenzhen 518060 Peoples R China;

    Shenzhen Univ Coll Phys &

    Optoelect Engn Dept One Inst One City One Country One Int Collab Minist Educ Shenzhen 518060 Peoples R China;

    Singapore Univ Technol &

    Design Pillar Engn Prod Dev 8 Somapah Rd Singapore 487371 Singapore;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 特种结构材料;
  • 关键词

    location-selective growth; NbS2/WS2 heterostructures; metallic TMDs;

    机译:位置选择性生长;NBS2 / WS2异质结构;金属TMDS;

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