Balanced energy density and power density: Asymmetric supercapacitor based on activated fullerene carbon soot anode and graphene-Co 3O 4 composite cathode

摘要

AbstractThe enhancement of energy density at high power density is highly desired in design of supercapacitor, which relies on the electrochemically accessible electrode area, electrons/ions diffusion channels of electrodes and the device assembly manner. Herein, graphitized and porous fullerene carbon soot is used as matrix for preparation of activated carbon (denoted as a-FC). The high specific surface area, hierarchical pore sizes and moderate graphitization degree of a-FC enable balanced specific capacitance, rate capability and cycleability. Meanwhile, graphene-Co3O4composite (GC) with cross-linked porous Co3O4nanofibers array onto graphene sheet is hydrothermally deposited on Ni foam substrate. The pseudocapacitive GC electrode can offer superior capacitance (1935 F?g?1at 5?A?g?1), rate capability (68% capacitance retaining ratio within 0.5–50?A?g?1) and considerable cycleability (17% capacitance decline within 2000 charge-discharge cycles) comprehensively. Furthermore, the asymmetric supercapacitor based on the a-FC and GC electrodes delivers balanced energy density (50.3–20.9?Wh kg?1), power density (786–12128?W?kg?1) and cycleability (77% initial capacitance maintaining ratio within 5000 charge-discharge cycles), highlighting the potential in efficient energy storage device.Graphical abstractDisplay OmittedHighlights?High electrons and ions conductivities of a-FC enable balanced capacitive properties.?Graphene-Co3O4composite with porous Co3O4nanofibers array on graphene was designed.?Balanced energy density and power density were achieved in asymmetric supercapacitor.]]>