Effects of MnO_2 and sintering temperature on microstructure, ferroelectric, and piezoelectric properties of Ba_(0.85_Ca _(0.15)Ti_(0.90)Zr_(0.10)O_3 lead-free ceramics

摘要

Ba_(0.85)Ca_(0.15)Ti_(0.90)Zr_(0.10)O _3 + xmol% MnO_2 lead-free ceramics have been prepared by a conventional sintering method and the effects of MnO_2 and sintering temperature on microstructure, ferroelectric, and piezoelectric properties of Ba_(0.85)Ca_(0.15)Ti_(0.90)Zr_(0.10)O _3 lead-free ceramics have been studied. The addition of 0.25 mol% MnO_2 promotes grain growth, improves the ferroelectricity of the ceramics and strengthens ferroelectric tetragonal-ferroelectric orthorhombic phase transition near 40 C. Because of the coexistence of tetragonal and orthorhombic phases and the combinatory effects of soft and hard doping of Mn ions, the ceramic with x = 0.25 exhibits the optimum piezoelectric properties (d _(33) = 306 pC/N and k _p = 42.2 %, respectively). Excess MnO_2 inhibits the grain growth and degrades the ferroelectric and piezoelectric properties of the ceramics. Sintering temperature has an important influence on the microstructure, tetragonal-orthorhombic phase transition near 40 °C, ferroelectric and piezoelectric properties of the ceramics. The increase in sintering temperature leads to large grains and more noticeable tetragonal-orthorhombic phase transition near 40 °C, enhances ferroelectricity and thus improves effectively the piezoelectricity of the ceramics. The Ba_(0.85)Ca_(0.15)Ti_(0.90)Zr 0.10O3 ceramic sintered at 1350 C possesses the optimum piezoelectric constant d _(33) value of 373 pC/N.