Furan-thiophene copolymers: Electrosynthesis and electrochemical behavior

摘要

The electrochemical copolymerization of furan and thiophene was performed at a constant electrode potential in a binary solvent system consisting of boron trifluoride/ethyl ether and an additional amount of ethyl ether (molar ratio = 1 : 2). The obtained homopolymers and copolymers were characterized with cyclic voltammetry and infrared spectroscopy. The influence of the applied electropolymerization potential and the monomer feed ratio of furan and thiophene on the copolymers was investigated. The furan-thiophene copolymers showed good stability of the redox activity in an acetonitrile-based electrolyte solution. (C) 2007 Wiley Periodicals, Inc.