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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Self-assembly of a 15-nickel metallamacrocyclic complex derived from the L-glutamic acid Schiff base ligand
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Self-assembly of a 15-nickel metallamacrocyclic complex derived from the L-glutamic acid Schiff base ligand

机译:自组装的L谷氨酸Schiff碱配体的15镍金属大环配合物的自组装

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摘要

An intriguing 15-nickel metallamacrocyclic complex, [Ni_(15)(EVan)_(10)-(H_2O)_(20)], 1 (EVan = Schiff base formed between L-glutamic acid and o-vanillin), has been synthesized and characterized by singlecrystal X-ray diffraction and spectroscopic analyses. 1 adopts a Ni-O-Ni-O-Ni-O configuration and can be divided into five discrete trinuclear units.
机译:有趣的15镍金属大环络合物[Ni_(15)(EVan)_(10)-(H_2O)_(20)] 1(EVan =由L-谷氨酸和邻香兰素形成的席夫碱)通过单晶X射线衍射和光谱分析合成和表征。 1采用Ni-O-Ni-O-Ni-O配置,可分为五个离散的三核单元。

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