Mechanistic Insight into Transition Metal-Catalyzed Reaction of Enynal/Enynone with Alkenes: Metal-Dependent Reaction Pathway

摘要

A systematic study of the transition metalcatalyzed reaction of enynal/enynone with alkenes has been reported. It was found that the reaction has two metaldependent reaction pathways. One led to the formation of 1,2- DHN, while another led to cyclic-o-QDM.