Nuclear Magnetic Resonance Study of Molecular Dynamics in Ammine Metal Borohydride Sr(BH4)(2)(NH3)(2)

摘要

We investigated molecular dynamics in Sr(BH4)(2)(NH3)(2), which is a representative compound for a series of ammine metal borohydrides, a novel family of systems exhibiting promising hydrogen storage properties with high hydrogen content and low decomposition temperature. Two types of hydrogen-containing groups present, namely, BH4 and NH3, prompt the investigation whether these materials differ from other borohydrides from a molecular dynamics point of view. The investigation was performed using H-1 and B-11 NMR spectroscopy and spin-lattice relaxation techniques. Different thermally activated reorientational processes of BH4 tetrahedra about their 2- and 3-fold symmetry axes were identified from temperature-dependent spin-lattice relaxation rates for both nuclei, and the corresponding activation energies were obtained. In addition, a selectively deuterated compound was studied to further distinguish the dynamic processes between both hydrogen-containing groups. Our study presents physical insight into the dynamic properties of Sr(BH4)(2)(NH3)(2) on a microscopic level of atomic groups, providing a link between the microscopic and bulk properties of this material.