Fluctuation/correlation effects in symmetric diblock copolymers: On the order-disorder transition

摘要

Using fast off-lattice Monte Carlo simulations with experimentally accessible fluctuations, we reported the first systematic study unambiguously quantifying the shift of the order-disorder transition (ODT) χ* of symmetric diblock copolymers from the mean-field prediction χ MF*. Our simulations are performed in a canonical ensemble with variable box lengths to eliminate the restriction of periodic boundary conditions on the lamellar period, and give the most accurate data of χ* and bulk lamellar period reported to date. Exactly the same model system (Hamiltonian) is used in both our simulations and mean-field theory; the ODT shift is therefore due to the fluctuations/correlations neglected by the latter. While χ*/χ MF*-1∝N?-k is found with N? denoting the invariant degree of polymerization, k decreases around the N?-value corresponding to the face-centered cubic close packing of polymer segments as hard spheres, indicating the short-range correlation effects.