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On the influence of a patterned substrate on crystallization in suspensions of hard spheres

机译:关于图案化基材对硬球悬浮液中结晶的影响

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We present a computer simulation study on crystal nucleation and growth in supersaturated suspensions of mono-disperse hard spheres induced by a triangular lattice substrate. The main result is that compressed substrates are wet by the crystalline phase (the crystalline phase directly appears without any induction time), while for stretched substrates we observe heterogeneous nucleation. The shapes of the nucleated crystallites fluctuate strongly. In the case of homogeneous nucleation amorphous precursors have been observed [T. Schilling et al., Phys. Rev. Lett. 105(2), 025701 (2010)]. For heterogeneous nucleation we do not find such precursors. The fluid is directly transformed into highly ordered crystallites.
机译:我们提出了一个计算机模拟研究的晶体成核和三角晶格衬底诱发的单分散硬球体的超饱和悬浮液中的生长。主要结果是受压的基材被结晶相弄湿(结晶相直接出现而没有任何诱导时间),而对于拉伸的基材,我们观察到异相形核。有核微晶的形状剧烈波动。在均匀成核的情况下,已经观察到非晶态前体[T。 Schilling等,Phys。牧师105(2),025701(2010)]。对于异质形核,我们没有找到这样的前体。流体直接转化为高度有序的微晶。

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