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Structure and effective interactions in parallel monolayers of charged spherical colloids

机译:带电球形胶体平行单层的结构和有效相互作用

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We study the microstructure and the effective interactions of model suspensions consisting of Yukawa-like colloidal particles homogeneously distributed in equally spaced parallel planar monolayers. All the particles interact with each other, but particle transfer between monolayers is not allowed. The spacing between the layers defines the effective system dimensionality. When the layer spacing is comparable to the particle size, the system shows quasi-three-dimensional behavior, whereas for large distances the layers behave as effective two-dimensional systems. We find that effective attractions between like-charged particles can be triggered by adjusting the interlayer spacing, showing that the distance between adjacent layers is an excellent control parameter for the effective interparticle interactions. Our study is based on Brownian dynamics simulations and the integral equations theory of liquids. The effective potentials are accounted for by exploiting the invariance of the Ornstein-Zernike matrix equation under contractions of the description, and on assuming that the difference between bare and effective bridge functions can be neglected. We find that the hypernetted chain approximation does not account properly for the effective interactions in layered systems.
机译:我们研究了由均匀分布在等间隔平行平面单层中的汤川样胶体颗粒组成的模型悬浮液的微观结构和有效相互作用。所有粒子都相互作用,但是不允许单层之间的粒子传输。层之间的间距定义了有效的系统尺寸。当层间距与颗粒尺寸相当时,系统显示准三维行为,而对于较大距离,层表现为有效的二维系统。我们发现,可以通过调节层间间距来触发带相似电荷的粒子之间的有效吸引,这表明相邻层之间的距离是有效粒子间相互作用的极佳控制参数。我们的研究基于布朗动力学模拟和液体积分方程理论。在描述的紧缩下,通过利用Ornstein-Zernike矩阵方程的不变性,并假设可以忽略裸桥和有效桥函数之间的差异,来说明有效电势。我们发现,超网状链近似不能正确解释分层系统中的有效交互作用。

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