Optical absorption from solvation-induced polarons on nanotubes

摘要

When an excess charge carrier is added to a one-dimensional (1D) wide-band semiconductor immersed in a polar solvent, the carrier can undergo self-localization into a large-radius adiabatic polaron. We explore the local optical absorption from the ground state of 1D polarons using a simplified theoretical model for small-diameter tubular structures. It is found that about 90% of the absorption strength is contained in the transition to the second lowest-energy localized electronic level formed in the polarization potential well, with the equilibrium transition energy larger than the binding energy of the polaron. Thermal fluctuations, however, can cause a very substantial-an order of magnitude larger than the thermal energy-broadening of the transition. The resulting broad absorption feature may serve as a signature for the optical detection of solvated charge carriers.