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On the glass temperature under extreme pressures

机译:在极端压力下的玻璃温度

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The application of a modified Simon-Glatzel-type relation [Z.Anorg.Allg.Chem.178,309 (1929)] for the pressure evolution of the glass temperature is presented,namely,T_g(P) = T_g~0[1+DELTA P/ (pi+P_g~0)]~(1/b) exp[-(DELTA P/c)],where (T_g~0,P_g~0) are the reference temperature and pressure,DELTA P = P-P_g~0,-pi is the negative pressure asymptote,b is the power exponent,and c is the damping pressure coefficient.The discussion is based on the experimental T_g(P) data for magmatic silicate melt albite,polymeric liquid crystal P8,and glycerol.The latter data are taken from Cook et al.[J.Chem.Phys.100,5178 (1994)] and from the authors' dielectric relaxation time (tau(P)) measurements,which employs the novel pressure counterpart of the Vogel-Fulcher-Tammann equation: tau(P) = tau_0~P exp[D_P DELTA P/(P0-P)],where DELTA P=P-P_(SL) (P_(SL) is the stability limit hidden under negative pressure),P0 is the estimation of the ideal glass pressure,and D_P is the isothermal fragility strength coefficient.Results obtained suggest the hypothetical maximum of the T_g(P) curve,which can be estimated due to the application of the supporting derivative-based analysis.A hypothetical common description of glass formers characterized by dT_g/dP>0 and dT_g/dP<0 coefficients is suggested.Finally,the hypothetical link between molecular and colloidal glass formers is recalled.
机译:提出了改进的Simon-Glatzel型关系式[Z.Anorg.Allg.Chem.178,309(1929)]在玻璃温度的压力演化中的应用,即T_g(P)= T_g〜0 [1 + DELTA P /(pi + P_g〜0)]〜(1 / b)exp [-(ΔP / c)],其中(T_g〜0,P_g〜0)是参考温度和压力,ΔP = P-P_g 〜0,-pi是负压渐近线,b是幂指数,c是阻尼压力系数。讨论基于岩浆硅酸盐熔融钠长石,聚合液晶P8和甘油的实验T_g(P)数据后一数据取自Cook等人[J.Chem.Phys.100,5178(1994)]和作者的介电弛豫时间(tau(P))测量,该测量采用了Vogel的新型压力对应物。 -Fulcher-Tammann方程:tau(P)= tau_0〜P exp [D_P DELTA P /(P0-P)],其中DELTA P = P-P_(SL)(P_(SL)是负压下隐藏的稳定性极限),P0是理想玻璃压力的估计值,D_P是等温脆性强度系数所获得的结果表明了T_g(P)曲线的假想最大值,该假想最大值可以通过基于辅助导数的分析方法进行估算.dD_g / dP> 0和dT_g / dP的玻璃成型体的假想通用描述建议使用<0系数。最后,我们回想起分子与胶态玻璃形成剂之间的假设联系。

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