An experimental and theoretical study of double photoionization of CF_4 using time-of-flight photoelectron-photoelectron (photoion-photoion) coincidence spectroscopy

摘要

Single photon double ionization of CF_4 has been studied by means of a time-of-flight photoelectron-photoelectron coincidence technique,which has very recently been extended towards ion detection,with energy analysis for the electrons and mass analysis for the ions.The complete single photon double ionization electron spectrum of CF_4 up to a binding energy of approx 51 eV is presented and discussed,also with the aid of accurate ab initio Green's function calculations.From ion detection in coincidence with the ejected electrons,we derive fragmentation pathway-selected double ionization electron spectra of CF_4.From the same data we extract the yield of each doubly charged ion or ion pair as a function of the double ionization energy.