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Phase tansitions in solutions of semiflexible polyelectrolytes

机译:半柔性聚电解质溶液中的相变

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Using a mean-field model, we have studied the phase behavior of a colection of semiflexible polyelectrolytes with electrostatic and anisotropic excluded volume interactions. The interference between the second-order critical phenomenon in the flexible limit and the first-order isotropic-nematic phase transition in th rod limit is found to be richly depenent on the intrinsic chain stiffness, polymer concentration, salt concentration, and temperature through the Flory-Huggins X parameter. For intrinsic chain stidffness below a critical value, there exists only a critical point and a coexistence curve between two isotropic phases. For smaller values of stiffness, but above the critical value, we have found a triple point corresponding to the coexistence of two isotropic phases and one anisotroic phase. As the chain stiffiness is increased progressively, the triple point moves towards lower polyelectrolyte concentration and approaches the critical point. If the chain stiffness is increasee even more, another triple point emerges corresponding the coexistence of oneisotropic phase and two anisotropic phases.
机译:使用平均场模型,我们研究了具有静电和各向异性排斥体积相互作用的半柔性聚电解质集合体的相行为。发现柔韧性极限中的二阶临界现象与杆极限中的一阶各向同性-向列相变之间的干扰取决于Flory的固有链刚度,聚合物浓度,盐浓度和温度-Huggins X参数。对于低于临界值的固有链刚度,在两个各向同性相之间仅存在一个临界点和一条共存曲线。对于较小的刚度值,但高于临界值,我们发现了一个三点,对应于两个各向同性相和一个各向异性相的共存。随着链刚度逐渐增加,三点移向较低的聚电解质浓度并接近临界点。如果链刚度进一步增加,则会出现另一个三点,对应于各向异性相和两个各向异性相的共存。

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