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Sound absorption in nonelectrolyte aqueous solutions

机译:非电解质水溶液中的吸声

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We indicate that the curve fitting for Debye-type relaxation spectrum of sound absorption (SA) cannot sufficiently account for the observed data of nonelectrolyte aqueous solutions (NEAS). To solve these problems, we introduce the distribution function of relaxation time [DFRT, F(#tau#)] from a diffusion equation of concentration fluctuations using the fluctuation theory. The SA expression is described by four-adjustable parameters. By use of the mixtures of 1-propanol, t-butanol, and monobutyl triethylene glycol with water, our calcualtion of SA shows the best fit between the observed and calculated curves, compared with other models. It was found that at lower frequencies the SA behaves as the square root of frequency. The aproximate expression of DFRT was expressed in terms of a power law of relaxation time, F(#tau#)~(propor. to) #tau#~(-#gamma#), which is the same as the expression of dielectric relaxation by Matsumoto and Higashi. Our exponent (#gamma#) of relaxation time is varied from 5/2 in hydrophilic solutes to /2 in hydrophobic solutes. The power (#gamma#) of relaxation time was regarded as a parameter to explain the hydrophobic and hydrophilic in the dissolved states of a solute. Our SA expression of #gamma#=5/2 for solutes of a small correlation length leads to that of Romanov-Solov'ev, where the value of 5/2 is that of the Debye distribution for the relaxation time in the Romanov-Solov'ev model.
机译:我们表明吸声(SA)的德拜型弛豫谱的曲线拟合不能充分说明非电解质水溶液(NEAS)的观测数据。为了解决这些问题,我们使用波动理论从浓度波动的扩散方程中引入了弛豫时间的分布函数[DFRT,F(#tau#)]。 SA表达式由四个可调参数描述。与其他模型相比,通过使用1-丙醇,叔丁醇和单丁基三甘醇与水的混合物,我们对SA的计算显示了所观察到的曲线与计算得出的曲线之间的最佳拟合。发现在较低频率下,SA表现为频率的平方根。 DFRT的近似表达是根据弛豫时间的幂定律F(#tau#)〜(正比于)#tau#〜(-#gamma#)表示的,它与介电弛豫的表达式相同松本和东。我们的松弛时间指数(#gamma#)从亲水性溶质的5/2变化到疏水性溶质的/ 2。弛豫时间的幂(#γ#)被认为是解释溶质溶解状态下的疏水性和亲水性的参数。对于较小相关长度的溶质,我们的SA表达式#gamma#= 5/2导致了Romanov-Solov'ev的SA表达式,其中5/2的值是Romanov-Solov中驰豫时间的Debye分布的值'ev模型。

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