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Nautre of polarized excitons

机译:极化激子的性质

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The electromagnetic interaction energy of a molecular aggregate consisting of pointlike molecules in the presence of an electromagnetic field is derived. The corresponding Hamiltonian consists of three parts; Ho describes the aggregate in the absence of the electromagnetic field,H 1 describes the interaction of the molecules with the external field, and H 2 corresponds to the induced interaction between the molecules. Based on this Hamiltonian we derive a self-consistent equation of motion for a quasiparticle, which we refer to as a polarized exciton. Th~ equation has the same form as the one in classical dipole theory .The polarized exciton model is based on a time-dependent perturbative treatment and corresponds to the assumption H o~ H 1 + H 2. Our model is compared to standard exciton theory , which is based on the assumption Ho~ H 2 ~ H 1 .In particular the differences and similarities are illustrated for a direct example, a finite linear chain. We advocate the use of polarized excitons to fully account for the physics in these systems.
机译:推导了在电磁场存在下由点状分子组成的分子聚集体的电磁相互作用能。相应的哈密顿量由三部分组成。 Ho描述了在没有电磁场的情况下的聚集体,H 1描述了分子与外场的相互作用,H 2对应于分子之间的感应相互作用。基于此哈密顿量,我们推导出了准粒子的自洽运动方程,我们称其为极化激子。 Th〜方程具有与经典偶极子理论相同的形式。极化激子模型基于时间相关的扰动处理,并且对应于假设H o〜H 1 + H 2。我们的模型与标准激子理论进行了比较,这是基于假设Ho〜H 2〜H 1的。特别是直接示例有限线性链的差异和相似之处。我们提倡使用极化激子来充分说明这些系统中的物理学。

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