首页> 外文期刊>The Journal of Chemical Physics >Inherent structures and nonequilibrium dynamics of one-dimensional constrained kinetic models:A comparison study
【24h】

Inherent structures and nonequilibrium dynamics of one-dimensional constrained kinetic models:A comparison study

机译:一维约束动力学模型的固有结构和非平衡动力学:比较研究

获取原文
获取原文并翻译 | 示例
           

摘要

We discuss the relevance of the Stillinger and Weber approach to the glass transition investigating the nonequilibrium behavior of models with nontrivial dynamics, but with simple equilibrium properties. We consider a family of iD constrained kinetic models, which interpolates between the asymmetric chain introduced by liickle and Eisinger lIZ. Phys. B 84, 115 (1991)] and the symmetric chain introduced by Fredrickson and Andersen [Phys. Rev. Lett 53, 1244 (1984)], and the iD version Qf the Backgammon model [Phys. Rev. Lett. 75, 1190 (1995)]. We show that the configurational entropy obtained from the inherent structures is the same for all models ilTespective of their different microscopic dynamics. We present a detailed study of the coarsening behavior of these models, including the relation between fluctuations and response. Our results suggest that any approach to the glass transit ion inspired by mean-field ideas and resting on the definition of a configurational entropy must rely on the absence of any growing characteristic coarsening pattern.
机译:我们讨论了Stillinger和Weber方法与玻璃化转变的相关性,玻璃化转变研究了具有非平凡动力学但具有简单平衡特性的模型的非平衡行为。我们考虑一族iD约束动力学模型,该模型插值在liickle和Eisinger lIZ引入的不对称链之间。物理B 84,115(1991)]和Fredrickson和Andersen提出的对称链[Phys。 Rev. Lett 53,1244(1984)]和iD版本Qf步步高模型[Phys。牧师75,1190(1995)]。我们表明,从固有结构获得的构型熵对于所有模型都是相同的,无论它们具有不同的微观动力学。我们对这些模型的粗化行为进行了详细的研究,包括波动与响应之间的关系。我们的结果表明,任何受到均值场思想启发并依赖于构型熵的定义的玻璃离子的方法,都必须依靠不存在任何增长的特征性粗化模式。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号