Synthetic studies toward eortriterpenoids of schisandraceae family. Approach to the construction of functloealized C/D and A/B ring units of micrandilactone C and rubriloradilactone B

摘要

Construction of 6/7 fused bicycles featuring C/D rings of micrandilactone C and rubrifloradilactone B is reported through IMDA reaction of properly designed substrates. Also a route to the construction of a tricycle having A/B ring of nortriterpenoids of schisandra family is reported using RCM and a bromonium ion initiated cycloetherification reaction as the key steps.