Preparation of a cationic bisoxazolinic nickel pincer catalyst and its applications to Michael addition and Mizoroki-Heck reaction

Koichi Mitsudo; Tatsuhiko Imura; Takashi Yamaguchi

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Preparation of a cationic bisoxazolinic nickel pincer catalyst and its applications to Michael addition and Mizoroki-Heck reaction

机译：阳离子双恶唑啉镍钳型催化剂的制备及其在迈克尔加成反应和Mizoroki-Heck反应中的应用

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Nickel pincer complex 1 was prepared by the treatment of nickel pincer 2 with AgBF4. Cationic nickel pincer complex 1 was air-stable and easy to handle, and was successfully applied to Michael addition and Mizoroki-Heck reaction.

机译：通过用AgBF 4处理镍钳2来制备镍钳复合物1。阳离子镍夹钳配合物1空气稳定且易于处理，已成功应用于迈克尔加成反应和Mizoroki-Heck反应。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2008年第51期|共3页
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Koichi Mitsudo; Tatsuhiko Imura; Takashi Yamaguchi;
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1. Preparation of a cationic bisoxazolinic nickel pincer catalyst and its applications to Michael addition and Mizoroki-Heck reaction [J] . Koichi Mitsudo, Tatsuhiko Imura, Takashi Yamaguchi Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2008,第51期

机译：阳离子双恶唑啉镍钳型催化剂的制备及其在迈克尔加成反应和Mizoroki-Heck反应中的应用
2. Synthesis and Structural Characterization of Nickel Complexes Possessing P-Stereogenic Pincer Scaffolds and Their Application in Asymmetric Aza-Michael Reactions [J] . Yang Zehua, Liu Delong, Liu Yangang, Organometallics . 2015,第7期

机译：含P-立体异构钳支架的镍配合物的合成，结构表征及其在不对称Aza-Michael反应中的应用
3. Highly dispersed nickel and palladium nanoparticle silica aerogels: sol-gel processing of tethered metal complexes and application as catalysts in the Mizoroki-Heck reaction [J] . Martinez S, Moreno-Manas M, Vallribera A, New Journal of Chemistry . 2006,第7期

机译：高度分散的镍和钯纳米粒子二氧化硅气凝胶：束缚金属配合物的溶胶-凝胶工艺及其在米佐罗基-赫克反应中的催化剂应用
4. Facile synthesis of a cationic bisoxazolinic nickel pincer catalyst and application as a catalyst for Mizoroki-Heck reaction and Michael addition [C] . Koichi Mitsudo, Tatsuhiko Irmira, Hideo Tanaka Symposium on Organometallic Chemistry . 2008

机译：阳离子双子唑啉镍磷酸镍催化剂的容易合成及其作为Mizoroki-Heck反应催化剂的应用和迈克尔
5. Palladium- and ruthenium-catalyzed decarboxylative allylations and Michael addition -allylation reactions. Applications in nitrogen heterocycle synthesis [D] . Wang, Chao 2008

机译：钯和钌催化的脱羧烯丙基化和迈克尔加成-烯丙基化反应。在氮杂环合成中的应用
6. Palladium(II)/Cationic 22’-Bipyridyl System as a Highly Efficient and Reusable Catalyst for the Mizoroki-Heck Reaction in Water [O] . Shao-Hsien Huang, Jun-Rong Chen, Fu-Yu Tsai 2010

机译：钯（II）/阳离子22-联吡啶系统是水中Mizoroki-Heck反应的高效且可重复使用的催化剂
7. Diaminoarylnickel(II) “Pincer” Complexes: Mechanistic Considerations in the Kharasch Addition Reaction, Controlled Polymerization, and Dendrimeric Transition Metal Catalysts [O] . Robert A. Gossage, Lucia A. van de Kuil, Gerard van Koten 1998

机译：DiaminoArdlnickel（ii）“钳子”复合物：Kharasch加成反应，受控聚合和树枝状过渡金属催化剂中的机械考虑

Preparation of a cationic bisoxazolinic nickel pincer catalyst and its applications to Michael addition and Mizoroki-Heck reaction

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