A stereoselective formal total synthesis of (+)-hyperaspine via a tandem aza-Michael reaction

Palakodety Radha Krishna; A.Sreeshailam

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A stereoselective formal total synthesis of (+)-hyperaspine via a tandem aza-Michael reaction

机译：通过串联aza-Michael反应进行立体选择性形式的（+）-高松碱全合成

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A stereoselective formal total synthesis of (+)-hyperaspine via a tandem aza-Michael reaction as the key step in good yield is reported.Hyperaspine 1,belongs to the class of ladybird alkaloids,isolated from Hyperaspia campestris possessing a unique 3-oxaquinolizidine skeleton.

机译：据报道，通过串联aza-Michael反应进行立体选择性正式合成（+）-高松碱是获得高收率的关键步骤。高松碱1属于瓢虫生物碱类，从具有独特的3-oxaquinolizidine骨架的桔小实蝇中分离得到。。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2007年第39期|共4页
作者
Palakodety Radha Krishna; A.Sreeshailam;
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(+)-Hyperaspine; 3-Oxaquinolizidine skeleton; Chiral allyl-ation; Dienone; One-pot double aza-Michael addition; Benzylamine.;

机译：（+）-Hyperaspine;3-氧杂喹啉骨架;手性烯丙基化;二烯酮;一锅双氮杂-Michael加成;苄胺。;

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1. A stereoselective formal total synthesis of (+)-hyperaspine via a tandem aza-Michael reaction [J] . Palakodety Radha Krishna, A.Sreeshailam Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2007,第39期

机译：通过串联aza-Michael反应进行立体选择性形式的（+）-高松碱全合成
2. A Highly Stereoselective Organocatalytic Tandem Aminoxylation/Aza-Michael Reaction for the Synthesis of Tetrahydro-1,2-Oxazines [J] . Zhu D, Lu M, Chua J, Organic letters . 2008,第20期

机译：高立体选择性有机催化串联氨氧化/氮杂-迈克尔反应合成四氢1,2-恶嗪。
3. Total synthesis of decytospolides A, B and a formal synthesis of aspergillide A starting from D-mannitol via tandem/domino reactions by Grubb's catalysts [J] . Kammari Bal Raju, Bejjanki Naveen Kumar, Kommu Nagaiah Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2015,第5a6期

机译：由Grubb的催化剂通过串联/多米诺反应从D-甘露醇开始全合成去细胞肽A，B和曲霉内酯A的正式合成
4. Development of Stereoselective Intramolecular Pummerer-typeReaction Towards the Total Synthesis of Parameritannin A2 [C] . Betkekar Vipul, Ohmori Ken, Suzuki Keisuke 日本化学会春季年会 . 2020

机译：立体选择性分子内翻盖物 - 逐渐发展朝向Parameritannin A2的总合成
5. I. Stereoselective Construction of Polycyclic Architectures: Enantioselective Catalytic Transannular Ketone-Ene Reactions and an Enantioselective Total Synthesis of (+)-Reserpine II. Synthesis of Chiral Bisthioureas for Anion-Abstraction Catalysis. [D] . Rajapaksa, Naomi Samadara. 2013

机译：I.多环结构的立体选择性构建：对映选择性催化环戊酮-烯反应和（+）-利血平的对映选择性总合成II。用于阴离子提取催化的手性双硫脲的合成。
6. Formal Synthesis of the ACE Inhibitor Benazepril·HCl via an Asymmetric Aza-Michael Reaction [O] . Luo-Ting Yu, Ji-Ling Huang, Ching-Yao Chang, 2006

机译：通过不对称的Aza-Michael反应正式合成ACE抑制剂Benazepril·HCl
7. HIGHLY STEREOSELECTIVE ALDOL-TYPE REACTION OF CHIRAL TIN(II) ENOLATE. FORMAL TOTAL SYNTHESIS OF (±)-THIENAMYCIN [O] . Nobuharu Iwasawa, Teruaki Mukaiyama 1986

机译：高度立体选择性醛醇型反应对手性锡（II）烯醇。正式总合成（±） - 硫霉素

A stereoselective formal total synthesis of (+)-hyperaspine via a tandem aza-Michael reaction

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