Synthesis of methyl 9-phenyl-7H-benzocycloheptene-6-carboxylates from Baylis-Hillman adducts:use of intramolecular Friedel-Crafts alkenylation reaction

Saravanan GowriSankar; Ka Young Lee; Chang Gon Lee; Jae Nyoung Kim

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Synthesis of methyl 9-phenyl-7H-benzocycloheptene-6-carboxylates from Baylis-Hillman adducts:use of intramolecular Friedel-Crafts alkenylation reaction

机译：由Baylis-Hillman加合物合成9-苯基-7H-苯并环庚烯-6-羧酸甲酯：分子内Friedel-Crafts烯基化反应的应用

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We developed a facile synthetic method for 9-phenyl-7H-benzocycloheptene derivatives from the Baylis Hillman adducts.Our method involved intramolecular Friedel-Crafts alkenylation reaction of triple bond-tethered methyl cinnamates.

机译：我们开发了一种从Baylis Hillman加合物合成9-苯基-7H-苯并环庚烯衍生物的简便方法，该方法涉及分子内三键连接甲基肉桂酸酯的Friedel-Crafts烯基化反应。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2004年第32期|共6页
作者
Saravanan GowriSankar; Ka Young Lee; Chang Gon Lee; Jae Nyoung Kim;
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baylis hiliman adducts; benzocycloheptene; friedel crafts alkenylation.;

机译：Baylis hiliman加合物;苯并环庚烯;Friedel工艺烯化。;

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1. Synthesis of methyl 9-phenyl-7H-benzocycloheptene-6-carboxylates from Baylis-Hillman adducts:use of intramolecular Friedel-Crafts alkenylation reaction [J] . Saravanan GowriSankar, Ka Young Lee, Chang Gon Lee, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2004,第32期

机译：由Baylis-Hillman加合物合成9-苯基-7H-苯并环庚烯-6-羧酸甲酯：分子内Friedel-Crafts烯基化反应的应用
2. One-Pot Synthesis of (E)-2-Arylideneindan-1-ones from the Baylis-Hillman Adducts via the Successive Inter- and Intramolecular Friedel-Crafts Reactions [J] . Hong Jung Lee, Jae Nyoung Kim, Taek Hyeon Kim Bulletin of the Korean Chemical Society . 2001,第10期

机译：通过连续的分子间和分子内Friedel-Crafts反应从Baylis-Hillman加合物一锅合成（E）-2-Arylideneindan-1-ones
3. Synthesis of 3,4-disubstituted 2(1H)-quinolinones via intramolecular Friedel-Crafts reaction of N-arylamides of Baylis-Hillman adducts [J] . Ko Hoon Kim, Hyun Seung Lee, Jae Nyoung Kim Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第11期

机译：通过Baylis-Hillman加合物的N-芳酰胺的分子内Friedel-Crafts反应合成3,4-二取代的2（1H）-喹啉酮
4. Ugi/Palladium-Catalysed Intramolecular Cyclopropyl Direct Alkenylation Cascade Reaction Providing Access to Azacycles [C] . Tianyi Shang, Yan Liu International Conference on Insulating Materials, Material Application and Electrical Engineering . 2019

机译：Ugi /钯催化的分子内环丙基直链烯基化级联反应，提供对氮杂的
5. Progress toward the synthesis of beta-branched Baylis-Hillman adducts via diastereoselective allenolate addition, and, Direct functionalization of tetrahydrofuran and other ethers with trimethylsilylketene, and, Synthesis and reactions of (eta6-phenyltricarbonylchromium)diazomethane. [D] . Rabbat, Christopher Joseph. 2006

机译：通过非对映选择性烯丙基酯加成合成β-支链Baylis-Hillman加合物的进展，以及四氢呋喃和其他醚与三甲基甲硅烷基烯酮的直接官能化，以及（eta6-苯基三羰基铬）重氮甲烷的合成和反应。
6. Stereoselective and Regioselective Intramolecular Friedel-Crafts Reaction of Aziridinium Ions for Synthesis of 4-Substituted Tetrahydroisoquinolines [O] . Hyun-Soon Chong, Yunwei Chen -1

机译：iri啶鎓离子的立体选择性和区域选择性分子内Friedel-Crafts反应用于合成4-取代的四氢异喹啉
7. Regioselective Synthesis of Fluorenones via the Consecutive In-Mediated Barbier Reaction, Pd-Catalyzed Cyclization, and Friedel-Crafts Reaction Starting from Baylis-Hillman Adducts [O] . Ko-Hoon Kim, Sung-Hwan Kim, Ka-Young Lee, 2011

机译：通过连续内介导的倒立剂反应，PD催化环化和Friedel-Crafts反应从Baylis-Hillman加合物开始的区域选择性合成

Synthesis of methyl 9-phenyl-7H-benzocycloheptene-6-carboxylates from Baylis-Hillman adducts:use of intramolecular Friedel-Crafts alkenylation reaction

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