A novel catalyzed C–H insertion reactions of hydrogen peroxide by poly(4-vinylpyridine)/methyltrioxorhenium systems

Gianluca Bianchini; Marcello Crucianelli; Francesco De Angelis; Veronica Neri; Raffaele Saladino

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A novel catalyzed C–H insertion reactions of hydrogen peroxide by poly(4-vinylpyridine)/methyltrioxorhenium systems

机译：聚（4-乙烯基吡啶）/甲基三氧杂hen鎓体系催化新型过氧化氢的CH插入反应

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摘要

Novel poly(4-vinylpyridine) supported MTO compounds were effective heterogeneous catalysts for the C–H insertion reactions of H_2O_2 into some representative hydrocarbon derivatives. The most relevant outcomes of these oxidations are described.

机译：新型的聚（4-乙烯基吡啶）负载的MTO化合物是有效的多相催化剂，可用于H_2O_2到某些代表性烃衍生物的C–H插入反应。描述了这些氧化的最相关结果。

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来源
《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2004年第11期|共3页
作者
Gianluca Bianchini; Marcello Crucianelli; Francesco De Angelis; Veronica Neri; Raffaele Saladino;
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正文语种 eng
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关键词
C–H insertion reaction; heterogeneous catalysis; hydrogen peroxide; methyltrioxorhenium;

机译：甲烷插入反应;多相催化;过氧化氢;甲基三氧or;

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1. A novel catalyzed C–H insertion reactions of hydrogen peroxide by poly(4-vinylpyridine)/methyltrioxorhenium systems [J] . Gianluca Bianchini, Marcello Crucianelli, Francesco De Angelis, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2004,第11期

机译：聚（4-乙烯基吡啶）/甲基三氧杂hen鎓体系催化新型过氧化氢的CH插入反应
2. Regioselective Synthesis of Phenols and Halophenols from Arylboronic Acids Using Solid Poly(N-vinylpyrrolidone)/Hydrogen Peroxide and Poly(4-vinylpyridine)/Hydrogen Peroxide Complexes [J] . G. K. Surya Prakash, Sujith Chacko, Chiradeep Panja Advanced synthesis & catalysis . 2009,第10期

机译：使用固体聚（N-乙烯基吡咯烷酮）/过氧化氢和聚（4-乙烯基吡啶）/过氧化氢配合物从芳基硼酸区域选择性合成苯酚和卤代酚
3. Regioselective Synthesis of Phenols and Halophenols from Arylboronic Acids Using Solid Poly(N-vinylpyrrolidone)/Hydrogen Peroxide and Poly(4-vinylpyridine)/Hydrogen Peroxide Complexes [J] . G. K. Surya Prakash, Sujith Chacko, Chiradeep Panja Advanced synthesis & catalysis . 2009,第10期

机译：使用固体聚（N-乙烯基吡咯烷酮）/氢过氧化氢和聚（4-乙烯基吡啶）/氢过氧化氢复合物从芳基硼酸的苯酚和卤代苯酚的区域选择性合成
4. THE HAZARD OF N-NITROSAMINES FORMATION DURING SHORT CHAIN SECONDARY AMINES (DMA, MEA AND DEA) REACTIONS WITH CATALYZED AND NON-CATALYZED HYDROGEN PEROXIDE [C] . P. ANDRZEJEWSKI, N. KULlK International Conference on Environmental Science and Technology . 2007

机译：催化和非催化过氧化氢的短链中仲胺（DMA，MEA和DEA）反应期间N-硝基胺形成的危害
5. Kinetics and mechanisms of the oxidation of alcohols and hydroxylamines by hydrogen peroxide, catalyzed by methyltrioxorhenium, MTO, and the oxygen binding properties of cobalt Schiff base complexes. [D] . Zauche, Timothy Harlan. 1998

机译：甲基三氧合hen，MTO催化过氧化氢氧化醇和羟胺的动力学和机理，以及钴席夫碱配合物的氧结合性能。
6. Selective Oxidation Reactions of Natural Compounds with Hydrogen Peroxide Mediated by Methyltrioxorhenium [O] . Maria E. Amato, Francesco P. Ballistreri, Andrea Pappalardo, 2013

机译：甲基三氧杂hen介导的天然化合物与过氧化氢的选择性氧化反应
7. Direct imaging of self-organized Comb copolymer-like systems obtained by hydrogen bonding: Poly(4-vinylpyridine)-4- nonadecylphenol:Poly(4-vinylpyridine)-4-Nonadecylphenol [O] . Ruokolainen J., Tanner J., Ikkala O., 1998

机译：通过氢键获得的自组织的梳状共聚物样体系的直接成像：聚（4-乙烯基吡啶）-4-十八烷基苯酚：聚（4-乙烯基吡啶）-4-壬基苯酚
8. Novel Applications of the Methyltrioxorhenium/Hydrogen Peroxide Catalytic System [R] . Stankovic, S. 2000

机译：甲基三氧铼/过氧化氢催化体系的新应用

A novel catalyzed C–H insertion reactions of hydrogen peroxide by poly(4-vinylpyridine)/methyltrioxorhenium systems

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