Diastereoselective synthesis of beta-substituted alpha-hydroxyphosphinates through hydrophosphinylation of alpha-heteroatom-substituted aldehydes

Yamagishi T.; Kusano T.; Kaboudin B.; Yokomatsu T.; Satuma C.; Shibuya S.

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Diastereoselective synthesis of beta-substituted alpha-hydroxyphosphinates through hydrophosphinylation of alpha-heteroatom-substituted aldehydes

机译：通过α-杂原子取代的醛的氢膦酰化进行β-取代的α-羟基次膦酸酯的非对映选择性合成

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The diastereoselective synthesis of beta-substituted alpha-hydroxyphosphinates was achieved by hydrophosphinylation of alpha-oxy aldehydes and alpha-amino aldehydes with ethyl allylphosphinate catalyzed by lithium phenoxide. (C) 2003 Elsevier Science Ltd. All rights reserved. [References: 27]

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《Tetrahedron 》 |2003年第6期| 共6页
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Yamagishi T.; Kusano T.; Kaboudin B.; Yokomatsu T.; Satuma C.; Shibuya S.;
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正文语种 eng
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Diastereoselection; Phosphinic acids and derivatives; Catalytic asymmetric-synthesis; Li-binol complex; Stereoselective synthesis; Chelation control; Aldol reactions; Acids; Phosphonates; Derivatives; Inhibitors; Additions;

机译：非对映体;膦酸及其衍生物;催化不对称合成;锂-联苯酚配合物;立体选择性合成;螯合控制;醛醇缩合反应;酸;膦酸酯;衍生物;抑制剂;添加剂;

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1. Diastereoselective synthesis of beta-substituted alpha-hydroxyphosphinates through hydrophosphinylation of alpha-heteroatom-substituted aldehydes [J] . Yamagishi T., Kusano T., Kaboudin B., Tetrahedron . 2003 ,第6期

机译：通过α-杂原子取代的醛的氢膦酰化进行β-取代的α-羟基次膦酸酯的非对映选择性合成
2. Diastereoselective Synthesis of Novel α-Amino-α′-hydroxyphosphinates by Hydrophosphinylation of α-Amino-H-phosphinates to Aldehydes [J] . Babak Kaboudin, Terumitsu Haruki, Takehiro Yamagishi, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2007 ,第20期

机译：通过α-氨基-H-次膦酸酯的氢膦化作用将非对映选择性合成新型α-氨基-α'-羟基次膦酸酯
3. Diastereoselective synthesis of chiral #beta#-amino-#alpha#-hydroxy-H-phosphinates through hydrophosphinylation of #alpha#-amino aldehydes [J] . Takehiro Yamagishi, Kenji Suemune, Tsutomu Yokomatsu, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001 ,第30期

机译：通过＃alpha＃-氨基醛的氢膦酰化进行手性＃beta＃-氨基-＃alpha＃-羟基-H-次膦酸酯的非对映选择性合成
4. Sulfonamide beta-ppetides.Synthesis and activity of For-Met-Leu-Phe-OMe analogues containing beta-substituted taurine residues [C] . Cesare Giordano, Susanna Di Segni, Susanna Spisani European Peptide Symposium . 2002

机译：磺酰胺β-ppetides。含有β取代的牛磺酸残留物的Met-Leu-Phe-OME类似物的合成和活性
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Synthesis of Polyoxygenated Heterocycles by Diastereoselective Functionalization of a Bio-Based Chiral Aldehyde Exploiting the Passerini Reaction [O] . Gabriella Vitali Forconesi, Luca Banfi, Andrea Basso, 2020

机译：基于生物基手性醛的非对映选择性官能化的聚氧化杂环的合成探索Passerini反应的基于生物的手性醛官能化
7. Copper-catalyzed regio- and enantioselective synthesis of chiral enol acetates and beta-substituted aldehydes [O] . Fananas-Mastral M., Feringa B.L. 2010

机译：铜催化手性烯醇乙酸酯和β-取代醛的区域和对映选择性合成

Diastereoselective synthesis of beta-substituted alpha-hydroxyphosphinates through hydrophosphinylation of alpha-heteroatom-substituted aldehydes

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