Evolution of morphology in electrodeposited nanocrystalline Co–Ni films by in-situ high magnetic field application

摘要

The effect of high magnetic fields up to 12 T, applied during electrodeposition process, on the morphology of nanocrystalline CoNi films has been investigated. The magneto-induced dramatic modifications in the morphology were observed by using field-emission scanning electronic micro- scopy and atomic force microscopy. Along with the increase of magnetic flux density (B), the grain size and the surface roughness of the films increased to reach a maximum value at a field of 9 T. Meanwhile, higher magnetic flux density could improve cobalt atomic percentage in the film due to the impacts of magnetohydrodynamic effect. However, at a high field of 12 T, the paramagnetic force played a predominant role in a decrease of mass transport, resulting in minimum grain size and roughness, even smaller than that of the ordinarily (B=0 T) sample.