Magnetic properties of anion-radical salt [Fe~(II)(dipy)_3](TCNQ)_4·(CH_3)_2CO

G. Vasylets; V.A. Starodub; A. Feher

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Magnetic properties of anion-radical salt [Fe~(II)(dipy)_3](TCNQ)_4·(CH_3)_2CO

机译：阴离子自由基盐[Fe〜（II）（dipy）_3]（TCNQ）_4·（CH_3）_2CO的磁性

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摘要

Magnetic properties of anion-radical TCNQ salt [Fe(dipy)_3](TCNQ)_4·(CH_3)_2CO have been investigated (dipy is 2,2'-dipyridil). X-ray diffraction data allow presence of two types of TCNQ stacks: tetramer-ized (diamagnetic) and partly dimerized (paramagnetic). Due to Mossbauer spectroscopy data iron cation appears as two-valent ion in low-spin state. Magnetic susceptibility temperature dependence is described by Bonner-Fischer model with additional weak impurity paramagnetism. Susceptibility curve is in good qualitative agreement with ESR spectra.

机译：研究了阴离子自由基TCNQ盐[Fe（dipy）_3]（TCNQ）_4·（CH_3）_2CO的磁性（dipy为2,2'-联吡啶。）。 X射线衍射数据允许存在两种类型的TCNQ堆栈：四聚体化（抗磁性）和部分二聚化（顺磁性）。由于使用了Mossbauer光谱，铁阳离子在低旋态下显示为二价离子。磁化率温度依赖性由Bonner-Fischer模型描述，具有附加的弱杂质顺磁性。磁化率曲线与ESR光谱具有良好的定性一致性。

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《Synthetic Metals 》 |2014年第null期| 共4页
作者
G. Vasylets; V.A. Starodub; A. Feher;
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正文语种 eng
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Tetracyanoquinodimethane; Mossbauer spectroscopy; Magnetic susceptibility;

机译：四甲基氨基喹二甲烷;莫斯鲍尔光谱;磁化率;

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1. Magnetic properties of anion-radical salt [Fe~(II)(dipy)_3](TCNQ)_4·(CH_3)_2CO [J] . G. Vasylets, V.A. Starodub, A. Feher Synthetic Metals . 2014 ,第Null期

机译：阴离子自由基盐[Fe〜（II）（dipy）_3]（TCNQ）_4·（CH_3）_2CO的磁性
2. 3](TCNQ) 4·X, where M?=?Co, Ni, Zn and X?=?H 2O or (CH 3) 2CO]]> [J] . D. ?oltésová, G. Vasylets, E. ?i?már, Inorganica Chimica Acta . 2018 ,第期

机译：<！[cdata [阴离子 - 自由基盐的磁性[m（bipy） 3 ]（tcnq） 4 x，其中m？=？co，ni，zn和x？place =“post”> 3 ） 2 CO]]>
3. Synthesis, Structure and Magnetic Properties of a Novel Anion-Radical Salt Based on TCNQ [J] . Ying Liu, Yu-Yong Xu, Guang-Xiang Liu, Journal of inorganic and organometallic polymers and materials . 2010 ,第1期

机译：基于TCNQ的新型阴离子基盐的合成，结构和磁性
4. SPECTRAL AND ELECTROPHYSICAL PROPERTIES OF ANION-RADICAL SALTS OF TCNQ AND METHYL-TCNQ WITH N-ALKYLPIRAZINIUM CATIONS [C] . Andrey V. Kravchenko, Vladimir A. Starodub, Alexander R. Kazachkov, NATO Advanced Research Workshop on Frontiers in Spectroscopy of Emerging Materials: Recent Advances toward New Technologies . 2004

机译：用N-烷基吡啶鎓阳离子的TCNQ和甲基-TCNQ阴离子盐的光谱和电神法性质
5. Studies of the structures and magnetic properties of some tetrahaloferrate(III) salts. [D] . Lowe, Carol Bistline. 1990

机译：研究某些四氟硼酸盐（III）盐的结构和磁性。
6. Stabilization of Pancake Bonding in (TCNQ)2.− Dimers in the Radical‐Anionic Salt (N−CH3−2‐NH2−5Cl−Py)(TCNQ)(CH3CN) Solvate and Antiferromagnetism Induction [O] . Dr. Tetiana N. Starodub, Dr. Erik Čižmár, Andrii Kliuikov, 2019

机译：（TCNQ）2中的薄煎饼粘结稳定.-自由基阴离子盐中的二聚体（N-CH3-2-NH2-5Cl-Py）（TCNQ）（CH3CN）溶剂化和反铁磁性
7. Studies on Dielectric and Conductive Properties of Polymeric Charge-Transfer Complexes. II. TCNQ Salts of Block Polymers Containing Polycation Sequences [O] . Shinobu Ikeno, Masaaki Yokoyama, Hiroshi Mikawa 1978

机译：聚合物电荷转移络合物介电和导电性能研究。 II。含有络合序列的嵌段聚合物的TCNQ盐
8. Magnetic Properties of N-Alkyl-Quinolinium(TCNQ) Sub 2 Complex Salts [R] . Ero-Gecs, M., Hung, P. T., Kuerti, J. 1981

机译：N-烷基喹啉（TCNQ）sub 2复合盐的磁性

Magnetic properties of anion-radical salt [Fe~(II)(dipy)_3](TCNQ)_4·(CH_3)_2CO

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