Addition of Sn-O'Pr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

Beletskiy Evgeny V.; Wu Yuyang; Kung Mayfair C.; Kung Harold H.

首页> 外文期刊>Organometallics >Addition of Sn-O'Pr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

【24h】

Addition of Sn-O'Pr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

机译：跨越C = C键的Sn-O'Pr的添加：烯烃不寻常地插入到主金属-醇键中

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

An example of unusual addition of a main group-metal alkoxide across an alkene C=C bond was demonstrated with a dimethylvinylsilyl-substituted Sn-POSS complex (POSS = incompletely condensed polyhedral oligomeric silsesquioxane). The structure of the pentacoordinated Sn chelate product was confirmed by H-1, C-13, and Sn-119 NMR and ESI-MS.

机译：用二甲基乙烯基甲硅烷基取代的Sn-POSS配合物（POSS =不完全缩合的多面体低聚倍半硅氧烷）证明了在烯烃C = C键上不常见地添加主族金属醇盐的例子。通过H-1，C-13和Sn-119 NMR和ESI-MS证实了五配位的Sn螯合物产物的结构。

著录项

来源
《Organometallics》 |2016年第3期|共2页
作者
Beletskiy Evgeny V.; Wu Yuyang; Kung Mayfair C.; Kung Harold H.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Addition of Sn-O'Pr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond [J] . Beletskiy Evgeny V., Wu Yuyang, Kung Mayfair C., Organometallics . 2016,第3期

机译：跨越C = C键的Sn-O'Pr的添加：烯烃不寻常地插入到主金属-醇键中
2. Insertion of an Alkene into an Ester: Intramolecular Oxyacylation Reaction of Alkenes through Acyl C-O Bond Activation [J] . Giang T. Hoang, Venkata Jaganmohan Reddy, Huy H. K. Nguyen Angewandte Chemie . 2011,第8期

机译：将烯烃插入酯中：通过酰基C-O键活化，烯烃的分子内氧化反应
3. Intramolecular Alkene Aminopalladation Reactions of (dppf)Pd(Ar)[N(Ar~1)(CH_2)_3CH=CH_2] Complexes. Insertion of Unactivated Alkenes into Pd-N Bonds [J] . Joshua D. Neukom, Nicholas S. Perch, John P. Wolfe Journal of the American Chemical Society . 2010,第18期

机译：（dppf）Pd（Ar）[N（Ar〜1）（CH_2）_3CH = CH_2]配合物的分子内烯烃氨基沉钯反应。将未活化的烯烃插入Pd-N键
4. Palladium-Catalyzed Alkene (or Alkyne) Insertion into Hydrogen-Transition Metal Bonds [C] . Nobuyuki Komine, Ayako Kuramoto, Kouhei Nakanishi Symposium on Organometallic Chemistry . 2006

机译：钯 - 催化烯烃（或炔烃）插入氢过渡金属键
5. Method Development for the Palladium-Catalyzed Synthesis of Nitrogen Heterocycles and Mechanistic Analysis of Migratory Alkene Insertion into Palladium-Nitrogen Bonds. [D] . Neukom, Joshua D. 2011

机译：钯催化氮杂环合成方法的发展以及迁移性烯烃插入钯氮键的机理分析。
6. Palladium-Catalyzed Synthesis of 21′-Disubstituted Tetrahydrofurans from γ-Hydroxy Internal Alkenes. Evidence for Alkene Insertion into a Pd-O bond and Stereochemical Scrambling via β-Hydride Elimination [O] . Michael B. Hay, John P. Wolfe -1

机译：钯催化由γ-羟基内烯烃合成21-二取代四氢呋喃。烯烃插入Pd-O键和通过消除β-氢化物的立体化学加扰的证据
7. Palladium-Catalyzed Synthesis of 2,1‘-Disubstituted Tetrahydrofurans from γ-Hydroxy Internal Alkenes. Evidence for Alkene Insertion into a Pd−O Bond and Stereochemical Scrambling via β-Hydride Elimination [O] . Michael B. Hay, John P. Wolfe 2005

机译：钯催化合成2,1'-二取代的四氢呋喃的γ-羟基烯烃。烯烃插入PD-O键的证据和通过β-氢化物消除的立体化学加扰

Addition of Sn-O'Pr across a C=C Bond: Unusual Insertion of an Alkene into a Main-Group-Metal-Alkoxide Bond

摘要

著录项

相似文献

相关主题

期刊订阅