Zinc(II) mediated imine-enamine tautomerization

Basa P.N.; Bhowmick A.; Horn L.M.; Sykes A.G.

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Zinc(II) mediated imine-enamine tautomerization

机译：锌（II）介导的亚胺-烯胺互变异构

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Reduction of imine-anthracenone compounds selectively produces secondary alcohols leaving the external imine group unreacted. Addition of the Zn(II) ion induces a metal-mediated imine-enamine tautomerization reaction that is selective for Zn(II), a new fluorescence detection method not previously observed for this important cation.

机译：亚胺-蒽酮化合物的还原选择性地产生仲醇，而使外部亚胺基未反应。 Zn（II）离子的添加会诱导对Zn（II）有选择性的金属介导的亚胺-烯胺互变异构反应，这是一种以前从未发现过的针对这种重要阳离子的新型荧光检测方法。

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《Organic letters》 |2012年第11期|共4页
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Basa P.N.; Bhowmick A.; Horn L.M.; Sykes A.G.;
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1. Zinc(II) mediated imine-enamine tautomerization [J] . Basa P.N., Bhowmick A., Horn L.M., Organic letters . 2012,第11期

机译：锌（II）介导的亚胺-烯胺互变异构
2. Dinuclear zinc(II) pyrazolates with different degrees of ring-fluorination and their use in zinc(II) mediated olefin aziridination [J] . Ponduru Tharun T., Dias H. V. Rasika Dalton transactions: An international journal of inorganic chemistry . 2017,第43期

机译：二核锌（II）吡唑酯，具有不同程度的环氟化锌及其在锌（II）介导的烯烃亚氮化中的用途
3. Deprotonation of zinc(II)-water and zinc(II)-alcohol and nucleophilicity of the resultant zinc(II) hydroxide and zinc(II) alkoxide in double-functionalized complexes: Theoretical studies on models for hydrolytic zinc enzymes [J] . Xia J., Shi YB., Zhang Y., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第1期

机译：锌（II）-水和锌（II）-醇的去质子作用以及所得的氢氧化锌（II）和锌（II）醇盐在双功能复合物中的亲核性：水解锌酶模型的理论研究
4. Indium zinc oxide mediated wafer bonding for III???V/Si tandem solar cells [C] . Tamboli Adele C., Essig Stephanie, Horowitz Kelsey A.W., IEEE Photovoltaic Specialists Conference . 2015

机译：铟锌氧化物介导的晶片键合用于Ⅲ，Ⅴ，V / Si串联太阳能电池
5. Zinc(II) mediated imine-enamine tautomerization as a new chemosensory protocol. [D] . Basa, Premnath. 2012

机译：锌（II）介导的亚胺-烯胺互变异构体作为一种新的化学传感方案。
6. Correction: Identification of an Acinetobacter baumannii Zinc Acquisition System that Facilitates Resistance to Calprotectin-mediated Zinc Sequestration [O] . M. Indriati Hood, Brittany L. Mortensen, Jessica L. Moore, 2013

机译：更正：鲍曼不动杆菌锌采集系统的鉴定该系统有助于抵抗钙卫蛋白介导的锌螯合
7. Experimental evidences in favour of the hydroxylamine→nitrene-water tautomerization on the coordination sphere of IrIII centres [O] . Cristóbal Crispín, López-Serrano Joaquín, Lozano-Vila Ana M., 2014

机译：在IrIII中心配位上有利于羟胺→硝烯-水互变异构的实验证据

Zinc(II) mediated imine-enamine tautomerization

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