Rh-2(OAc)(4)-AgOTf Cooperative Catalysis in Cyclization/Three-Component Reactions for Concise Synthesis of 1,2-Dihydroisoquinolines

Guo ZQ; Cai M; Jiang J; Yang LP; Hu WH

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Rh-2(OAc)(4)-AgOTf Cooperative Catalysis in Cyclization/Three-Component Reactions for Concise Synthesis of 1,2-Dihydroisoquinolines

机译：Rh-2（OAc）（4）-AgOTf协同催化环化/三组分反应，合成1,2-二氢异喹啉

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摘要

Dirhodium acetate and silver triflate cooperatively catalyzed tandem cyclization/three-component reactions of 2-alkynylarylaldimines with diazo compounds and water or alcohols are reported to afford 1,2-dihydroisoquinolines bearing alpha-hydroxyl-beta-amino carboxylate skeleton in high yield.

机译：据报道，乙酸铱和三氟甲磺酸银协同催化2-炔基芳基亚胺与重氮化合物和水或醇的串联环化/三组分反应，可高产率提供带有α-羟基-β-氨基羧酸盐骨架的1,2-二氢异喹啉。

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《Organic letters 》 |2010年第4期| 共4页
作者
Guo ZQ; Cai M; Jiang J; Yang LP; Hu WH;
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正文语种 eng
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TANDEM NUCLEOPHILIC-ADDITION; ALCOHOLIC OXONIUM YLIDE; 3-COMPONENT REACTION; ARYL DIAZOACETATES; PRIMARY AMINES; C-H; ALDEHYDES; IMINES; CARBENOIDS; EFFICIENT;

机译：串联核键加成;醇氧代氧化IDE;3-组分反应;芳族重氮酸盐;初级酰胺;C-H;丙二醛;亚胺;类胡萝卜素;高效;

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1. Rh-2(OAc)(4)-AgOTf Cooperative Catalysis in Cyclization/Three-Component Reactions for Concise Synthesis of 1,2-Dihydroisoquinolines [J] . Guo ZQ, Cai M, Jiang J, Organic letters . 2010 ,第4期

机译：Rh-2（OAc）（4）-AgOTf协同催化环化/三组分反应，合成1,2-二氢异喹啉
2. Three-component reactions based on trapping ammonium ylides with N-sulfonyl aldimines via cooperative catalysis of squaramides and Rh_2(OAc)_4 [J] . Lin Qiu, Dongwei Wang, Fengping Lv, Tetrahedron . 2014 ,第7期

机译：基于三酰胺和Rh_2（OAc）_4协同催化的N-磺酰基醛亚胺捕集铵盐的三组分反应
3. Three-component reactions based on trapping ammonium ylides with N-sulfonyl aldimines via cooperative catalysis of squaramides and Rh_2(OAc)_4 [J] . Lin Qiu, Dongwei Wang, Fengping Lv, Tetrahedron . 2014 ,第7期

机译：基于三酰胺和Rh_2（OAc）_4协同催化的N-磺酰基醛亚胺捕集铵盐的三组分反应
4. Palladium-Catalyzed Cycloaddition of Chloroform to o-Alkynylaryl Aldimines: Synthesis of 1-Trichloro-1,2-dihydroisoquinolines [C] . Hiroyuki Saito, Hiroyuki Nakamura Symposium on Organometallic Chemistry . 2007

机译：钯催化的氯仿环加成氯仿至O-炔基族醛喹啉：1-三氯-1,2-二羟基喹啉的合成
5. Synthesis of (1R,2R)-N1,N2-Dibenzylcyclohexane-1,2-diamine as an Auxiliary for a Stereoselective 1,4 Conjugate Addition Reaction; Construction of Polymer Bound (1R,2R)- 1,2-Cyclohexanediamine to evaluate the Solid-Phase Counterpart, and Methodology Development for Synthesis of Functionalized Oligothiophenes. [D] . Poorjahanshah, Homer. 2016

机译：（1R，2R）-N1，N2-二苄基环己烷-1，2-二胺作为立体选择性1，4共轭加成反应的助剂的合成；聚合物结合的（1R，2R）-1,2-环己二胺的构建以评价固相配对物，以及功能化寡聚噻吩的合成方法开发。
6. Development of Novel and Efficient Processes for the Synthesis of 5-Amino and 5-Iminoimidazo[1,2-a]imidazoles via Three-Component Reaction Catalyzed by Zirconium(IV) Chloride [O] . Mohsine Driowya, Régis Guillot, Pascal Bonnet, 1970

机译：氯化锆（IV）催化三组分反应合成5-氨基和5-氨基咪唑并[1,2-a]咪唑的新颖高效方法的进展
7. Concise Synthesis of 1,2-Dihydroisoquinolines and 1H-Isochromenes by Carbophilic Lewis Acid-Catalyzed Tandem Nucleophilic Addition and Cyclization of 2-(1-Alkynyl)arylaldimines and 2-(1-Alkynyl)arylaldehydes [O] . -1

机译：通过Carbophilic Lewis酸催化的串联亲核加成和2-（1-炔基）芳基二氧化胺和2-（1-炔基）芳基的环化合成1,2-二羟基喹啉和1H-异氧化物的合成

Rh-2(OAc)(4)-AgOTf Cooperative Catalysis in Cyclization/Three-Component Reactions for Concise Synthesis of 1,2-Dihydroisoquinolines

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