Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides

Ishida N; Shimamoto Y; Murakami M

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Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides

机译：立体选择性合成（E）-（三取代烯基）硼酸酯：在钯催化的炔基硼酸酯与芳基卤化物的钯催化反应中，配体逆转的立体化学

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The palladium-catalyzed reaction of alkynylborates with aryl halides stereoselectively gave (E)-(trisubstituted alkenyl)-9-BBNs, In which two different aryl groups were Installed trans to each other.

机译：炔基硼酸酯与芳基卤化物的钯催化反应立体选择得到（E）-（三取代烯基）-9-BBN，其中两个不同的芳基彼此反式安装。

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《Organic letters》 |2009年第23期|共4页
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Ishida N; Shimamoto Y; Murakami M;
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正文语种 eng
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TETRASUBSTITUTED OLEFINS; ORGANOBORON COMPOUNDS; (Z)-TAMOXIFEN; DERIVATIVES; CARBOMETALATION; REARRANGEMENT; COMPLEXES; TAMOXIFEN; POLYMERS; STRATEGY;

机译：四取代烯烃;有机硼化合物;（Z）-他莫昔芬;衍生物;羰基化;重排;络合物;他莫昔芬;聚合物;策略;

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1. Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides [J] . Ishida N, Shimamoto Y, Murakami M Organic letters . 2009,第23期

机译：立体选择性合成（E）-（三取代烯基）硼酸酯：在钯催化的炔基硼酸酯与芳基卤化物的钯催化反应中，配体逆转的立体化学
2. Synthesis of Aziridines by Palladium-Catalyzed Reactions of Allylamines with Aryl and Alkenyl Halides: Evidence of a syn-Carboamination Pathway [J] . Sayuri Hayashi, Hideki Yorimitsu, Koichiro Oshima Angewandte Chemie . 2009,第39期

机译：烯丙基胺与芳基和烯基卤化物的钯催化反应合成氮丙啶：合成碳氨基化途径的证据
3. A novel stereoselective synthesis of trisubstituted 1,3-dienes by a hydrostannylation-Stille tandem reaction of alkylarylacetylenes with alkenyl halides [J] . Hean Zhang, Yan Yu, Wenyan Hao, Journal of chemical research: reviews and research papers from all branches of chemistry . 2010,第3期

机译：烷基芳基乙炔与烯基卤化物的加氢苯乙烯基化-斯蒂尔级联反应的新型立体选择性合成三取代的1,3-二烯
4. Stereoselective Synthesis of Trisubstituted Alkenylboranes by Palladium-Catalyzed Reaction of Alkynyltriarylborates with Aryl Halides [C] . Naoki Ishida, Tatsuo Shinmoto, Tomoya Miura Symposium on Organometallic Chemistry . 2007

机译：钯催化反应与芳基卤化物的钯催化反应的立体选择性合成羟基芳基芳基硼酸盐的反应
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. Applications of 1-Alkenyl-11-Heterobimetallics in the Stereoselective Synthesis of Cyclopropylboronate Esters Trisubstituted Cyclopropanols and 23-Disubstituted Cyclobutanones [O] . Mahmud M. Hussain, Hongmei Li, Nusrah Hussain, -1

机译：1-烯-11- Heterobimetallics在Cyclopropylboronate酯的立体选择性合成三取代Cyclopropanols和23-二取代的Cyclobutanones应用
7. Synthesis of 1-Alkenylboronic Esters via Palladium-Catalyzed Cross-Coupling Reaction of Bis(pinacolato)diboron with 1-Alkenyl Halides and Triflates [O] . Takahashi, Kou, Takagi, Jun, Ishiyama, Tatsuo, 2000

机译：双（频哪醇）二硼与1-烯基卤化物和三氟甲磺酸酯的钯催化交叉偶联反应合成1-烯基硼酸酯
8. Aryl Bis(triflates) in Palladium (0) Cross-Coupling Reactions. Synthesis ofPolyphenyl-Alkynyl, Alkenyl, and Aryl Ethers [R] . Wright, M. E. 1991

机译：钯（0）交叉偶联反应中的芳基双（三氟甲磺酸酯）。聚苯基 - 炔基，烯基和芳基醚的合成

Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides

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