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首页> 外文期刊>Langmuir: The ACS Journal of Surfaces and Colloids >Molecular Dynamics Simulations on Coalescence and Non-coalescence of Conducting Droplets
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Molecular Dynamics Simulations on Coalescence and Non-coalescence of Conducting Droplets

机译:导电液滴聚结与非聚结的分子动力学模拟

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摘要

When an electric field with various strengths is applied to two adjacent conducting droplets, the droplets may completely coalesce, partially coalesce, or bounce off one another. To reveal an atom-scale mechanism of coalescence or non-coalescence, dynamic behaviors of two conducting nanodroplets at a homogeneous electric field are studied via, molecular dynamics simulations in this work. The results show that there is a critical field strength and a critical cone angle above which the two droplets partially coalesce or bounce off. Charge transfer between the two droplets is observed when the droplets are brought into contact. The partial coalescence and the bounce-off of the two droplets at strong field strengths are found to be due to the high charge transfer rate, which leads to the breakup of the coalescing droplet at different locations.
机译:当将具有不同强度的电场施加到两个相邻的导电液滴上时,液滴可能会完全聚结,部分聚结或彼此反弹。为了揭示聚结或非聚结的原子尺度机理,在这项工作中,通过分子动力学模拟研究了两个导电纳米液滴在均匀电场下的动力学行为。结果表明存在临界场强和临界锥角,在该临界角和临界锥角以上,两个液滴部分聚结或弹起。当液滴接触时,观察到两个液滴之间的电荷转移。发现在强场强下两个液滴的部分聚结和弹起是由于高的电荷转移速率导致的,这导致聚结的液滴在不同的位置破裂。

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